(d,l)-2,3,4-trimethyl-2,3-dihydroxycyclopentanone methylene acetal silyl enol ether

Base Information

• Chemical Name: (d,l)-2,3,4-trimethyl-2,3-dihydroxycyclopentanone methylene acetal silyl enol ether
• CAS No.: 109391-30-2
• Molecular Formula: C₁₅H₂₈O₃Si
• Molecular Weight: 284.471
• Mol file: 109391-30-2.mol

Synonyms:(d,l)-2,3,4-trimethyl-2,3-dihydroxycyclopentanone methylene acetal silyl enol ether

Chemical Property of (d,l)-2,3,4-trimethyl-2,3-dihydroxycyclopentanone methylene acetal silyl enol ether

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of (d,l)-2,3,4-trimethyl-2,3-dihydroxycyclopentanone methylene acetal silyl enol ether

There total 1 articles about (d,l)-2,3,4-trimethyl-2,3-dihydroxycyclopentanone methylene acetal silyl enol ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2,3,4-trimethylcyclopent-2-en-1-one (28790-86-5) → (d,l)-2,3,4-trimethyl-2,3-dihydroxycyclopentanone methylene acetal silyl enol ether (109391-30-2)

Guidance literature:

Multi-step reaction with 3 steps

1: 1.) OsO₄, 2.) HS(CH₂)2CO₂H / 1.) -95 deg C

2: 93 percent / P₂O₅

3: 93 percent / KHMDS

With osmium(VIII) oxide; phosphorus pentoxide; potassium hexamethylsilazane; 3-mercaptopropionic acid;

DOI:10.1021/jo00226a045

upstream raw materials:

2,3,4-trimethylcyclopent-2-en-1-one

Refernces