Silacyclobutane

Base Information

• Chemical Name: Silacyclobutane
• CAS No.: 287-29-6
• Molecular Formula: C3H8 Si
• Molecular Weight: 72.182
• DSSTox Substance ID: DTXSID60883356
• Wikipedia: Silacyclobutane
• Mol file: 287-29-6.mol

Synonyms:Silacyclobutane;Silicetane;287-29-6;BRN 0605286;DTXSID60883356;MFCD01684283;AKOS006277355;LS-144862

Chemical Property of Silacyclobutane

Chemical Property:

• Vapor Pressure: 641mmHg at 25°C
• Boiling Point: 29.8°Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: 0.39550
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 70.023876726
• Heavy Atom Count: 4
• Complexity: 17.2

Purity/Quality:

99% ^*data from raw suppliers

SILACYCLOBUTANE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1C[Si]C1

Technology Process of Silacyclobutane

There total 2 articles about Silacyclobutane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

1,1-dichlorosilacyclobutane (2351-33-9) → siletane (287-29-6)

Guidance literature:

With lithium aluminium tetrahydride; In dibutyl ether; -23 deg C, then room t.;

DOI:10.1021/ja00256a025

Reference yield:

→ siletane (287-29-6)

Guidance literature:

Reference yield: 84.0%

siletane (287-29-6) → 1,1-dichlorosilacyclobutane (2351-33-9) + 1-chloro-1-methylsilacyclobutane (20156-49-4)

Guidance literature:

With silver(I) chloride; at 50 ℃; AgCl column, rate = 3 mL/h, 5 passes;

DOI:10.1021/j100219a012

upstream raw materials:

1,1-dichlorosilacyclobutane

Downstream raw materials:

ethene

polycarbosilane

1,3-disilacyclobutane

silacyclobutadiene

Refernces

• 1、 Melandri, Sonia,Favero, Laura B.,Caminati, Walther,Grosser, M.,Dakkouri, Marwan. "Conformational Equilibrium in 1-Fluoro-1-silacyclobutane as Studied by Microwave Spectroscopy and ab Initio Calculations". . p. 223 - 236. Retrieved 1995.
• 2、 Dakkouri,Grosser. "Structural and conformational analysis of 1-monofluorosilacyclobutane and 1-monochlorosilacyclobutane. A gas-phase electron diffraction and ab initio investigation". . p. 7 - 24. Retrieved 2007/10/03.