2-heptyl-1-methoxybenzene

Base Information

• Chemical Name: 2-heptyl-1-methoxybenzene
• CAS No.: 104941-42-6
• Molecular Formula: C₁₄H₂₂O
• Molecular Weight: 206.328
• Mol file: 104941-42-6.mol

Synonyms:2-heptyl-1-methoxybenzene

Chemical Property of 2-heptyl-1-methoxybenzene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-heptyl-1-methoxybenzene

There total 9 articles about 2-heptyl-1-methoxybenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

1-(2-methoxyphenyl)heptan-1-ol (104941-44-8) → 2-heptyl-1-methoxybenzene (104941-42-6)

Guidance literature:

With triethylsilane; sodium hydrogencarbonate; trifluoroacetic acid; In dichloromethane; at 20 ℃; for 1h; Inert atmosphere;

DOI:10.1016/j.bmc.2013.10.051

Reference yield: 65.0%

1-Iodoheptane (4282-40-0) + 2-bromoanisole (578-57-4) → 2-heptyl-1-methoxybenzene (104941-42-6)

Guidance literature:

With N,N,N,N,-tetramethylethylenediamine; bis(di-tert-?butyl(4-?dimethylaminophenyl)?phosphine)?dichloropalladium(II); zinc; In water; at 20 ℃; for 24h; Inert atmosphere;

DOI:10.1021/ja906803t

Reference yield:

2-Chloroanisole (766-51-8) + n-heptylmagnesium bromide (13125-66-1) → 2-heptyl-1-methoxybenzene (104941-42-6)

Guidance literature:

With 1,3-bis[(diphenylphosphino)propane]dichloronickel(II); In diethyl ether; Heating;

DOI:10.1021/ja003124k

upstream raw materials:

1-heptyl 4-methylbenzenesulfonate

2-bromoanisole

2-Chloroanisole

n-heptylmagnesium bromide

Downstream raw materials:

ortho-heptylphenol

ethyl 2-(4-bromo-2-heptylphenoxy) acetate

2-heptyl-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenol

1-Brom-3-(2-n-heptylphenoxy)-propan

Refernces

• 1、 Bouchoux, Guy,Sablier, Michel,Miyakoshi, Tetsuo,Honda, Takashi. "A 'meta effect' in the fragmentation reactions of ionised alkyl phenols and alkyl anisoles". scheme or table. p. 539 - 546. Retrieved 2012/09/22.
• 2、 Koelbel,Beyersdorff,Xiao Hong Cheng,Tschierske,Kain,Diele. "Design of liquid crystalline block molecules with nonconventional mesophase morphologies: Calamitic bolaamphiphiles with lateral alkyl chains". . p. 6809 - 6818. Retrieved 2007/10/03.