lithium 1-phenylethenolate

Base Information

• Chemical Name: lithium 1-phenylethenolate
• CAS No.: 1052762-47-6
• Molecular Formula: C₈H₇LiO
• Molecular Weight: 126.084
• Mol file: 1052762-47-6.mol

Synonyms:lithium 1-phenylethenolate

Chemical Property of lithium 1-phenylethenolate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of lithium 1-phenylethenolate

There total 3 articles about lithium 1-phenylethenolate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

acetophenone (98-86-2) → lithium 1-phenylethenolate (1052762-47-6)

Guidance literature:

With n-butyllithium; diisopropylamine; In tetrahydrofuran; hexane; at -78 ℃; for 2h;

DOI:10.1021/jo00298a047

Reference yield:

1-styrenyloxytrimethylsilane (13735-81-4) → lithium 1-phenylethenolate (1052762-47-6)

Guidance literature:

With n-butyllithium; In diethyl ether; hexane; for 1.5h; Ambient temperature;

DOI:10.1016/0022-328X(90)87280-Q

Reference yield:

→ lithium 1-phenylethenolate (1052762-47-6)

Guidance literature:

DOI:10.1021/jo00821a034

upstream raw materials:

1-styrenyloxytrimethylsilane

acetophenone

Downstream raw materials:

2-(2-Oxo-2-phenyl-ethyl)-2H-pyridine-1-carboxylic acid phenyl ester

4-(2-Oxo-2-phenyl-ethyl)-4H-pyridine-1-carboxylic acid phenyl ester

2-Methyl-4-(2-oxo-2-phenyl-ethyl)-4H-pyridine-1-carboxylic acid phenyl ester

6-Methyl-2-(2-oxo-2-phenyl-ethyl)-2H-pyridine-1-carboxylic acid phenyl ester

Refernces

• 1、 Besten, Remco den,Harder, Sjoerd,Brandsma, Lambert. "A method for the determination of the degree of association of organolithium compounds in liquid ammonia". . p. 153 - 159. Retrieved 1990.
• 2、 Nakayama, Juzo,Otani, Takashi,Sugihara, Yoshiaki,Ishii, Akihiko. "Ambident reactivities of bis(diethylamino)[(methylthio)thiocarbonyl]carbenium salts; reactions at the carbenium carbon atom vs. thiocarbonyl sulfur atom". . p. 5013 - 5016. Retrieved 1997.
• 3、 Kolonko, Kristopher J.,Biddle, Margaret M.,Guzei, Ilia A.,Reich, Hans J.. "Solution structures of lithium enolates of cyclopentanone, cyclohexanone, acetophenones, and benzyl ketones. Triple ions and higher lithiate complexes". supporting information; experimental part. p. 11525 - 11534. Retrieved 2011/02/26.