Methyl cumyl ether

Base Information

• Chemical Name: Methyl cumyl ether
• CAS No.: 935-67-1
• Molecular Formula: C10H14 O
• Molecular Weight: 150.221
• Hs Code.: 2909309090
• European Community (EC) Number: 213-306-6
• DSSTox Substance ID: DTXSID6061319
• Nikkaji Number: J125.038H
• Wikidata: Q81989407
• Mol file: 935-67-1.mol

Synonyms:Methyl cumyl ether;935-67-1;2-methoxypropan-2-ylbenzene;(1-Methoxy-1-methylethyl)benzene;2-Methoxy-2-phenylpropane;Benzene, (1-methoxy-1-methylethyl)-;Methyl alpha,alpha-dimethylbenzyl ether;EINECS 213-306-6;alpha,alpha-Dimethylbenzyl methyl ether;Ether, .alpha.,.alpha.-dimethylbenzyl methyl;cumyl methyl ether;2-Phenyl-2-methoxypropane;SCHEMBL42639;SCHEMBL7644970;DTXSID6061319;(1-Methoxy-1-methylethyl)benzene #;AKOS024336761;.alpha.,.alpha.-Dimethylbenzyl methyl ether

Chemical Property of Methyl cumyl ether

Chemical Property:

• Vapor Pressure: 1.18mmHg at 25°C
• Boiling Point: 181.1°Cat760mmHg
• Flash Point: 58.8°C
• PSA: 9.23000
• Density: 0.924g/cm³
• LogP: 2.56810
• XLogP3: 3.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 150.104465066
• Heavy Atom Count: 11
• Complexity: 112

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CC(C)(C1=CC=CC=C1)OC
• Uses: (1-Methoxy-1-methylethyl)benzeneis used in the preparation and characterization of graphene sheet/polymeric carbon nitride nanocomposites as metal-free catalysts for hydrocarbon oxidization.

Technology Process of Methyl cumyl ether

There total 44 articles about Methyl cumyl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

methanol (67-56-1) + 1-methyl-1-phenylethyl alcohol (617-94-7) → Cumyl methyl ether (935-67-1)

Guidance literature:

With hydrogenchloride; In water; at 20 ℃; for 320h; chemoselective reaction;

DOI:10.1134/S107042801509002X

Reference yield: 100.0%

methanol (67-56-1) + isopropenylbenzene (98-83-9,6144-04-3,25014-31-7,42612-14-6) → Cumyl methyl ether (935-67-1)

Guidance literature:

With C₂₄H₂₆N₂S; at 30 ℃; for 20h; Reagent/catalyst; Catalytic behavior; UV-irradiation;

DOI:10.3762/bjoc.15.5

Reference yield: 87.0%

methanol (67-56-1) + Dimethyl-[4-(1,1,2-trimethyl-2-phenyl-propyl)-phenyl]-amine → Cumyl methyl ether (935-67-1) + [4-(1-Methoxy-1-methyl-ethyl)-phenyl]-dimethyl-amine + isopropenylbenzene (98-83-9,6144-04-3,25014-31-7,42612-14-6)

Guidance literature:

With tris-(4-bromophenyl)aminium hexachloroantimonate; In dichloromethane; at -20.1 ℃; Thermodynamic data; ΔH(excit), ΔS(excit);

DOI:10.1021/ja00232a062

upstream raw materials:

methanol

cumenyl chloride

2-bromo-2-phenylpropane

isopropenylbenzene

Downstream raw materials:

isopropylbenzene-d1

bineophyl

cumyl potassium

cumyl azide

Refernces

• 1、 Seyfert, Fabienne,Wagenknecht, Hans-Achim. "N -Arylbenzo[ b ]phenothiazines as Reducing Photoredox Catalysts for Nucleophilic Additions of Alcohols to Styrenes: Shift towards Visible Light". supporting information. p. 582 - 586. Retrieved 2021/01/25.
• 2、 Oyama, Ryoko,Abe, Manabu. "Reactivity and Product Analysis of a Pair of Cumyloxyl and tert-Butoxyl Radicals Generated in Photolysis of tert-Butyl Cumyl Peroxide". . p. 8627 - 8638. Retrieved 2020/07/21.