N,N-dibutyl-P,P-diphenylphosphinous amide

Base Information

• Chemical Name: N,N-dibutyl-P,P-diphenylphosphinous amide
• CAS No.: 13998-69-1
• Molecular Formula: C₂₀H₂₈NP
• Molecular Weight: 313.423
• Mol file: 13998-69-1.mol

Synonyms:N,N-dibutyl-P,P-diphenylphosphinous amide

Chemical Property of N,N-dibutyl-P,P-diphenylphosphinous amide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N,N-dibutyl-P,P-diphenylphosphinous amide

There total 3 articles about N,N-dibutyl-P,P-diphenylphosphinous amide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

dibutylamine (111-92-2) + chloro-diphenylphosphine (1079-66-9,74391-44-9) → N,N-dibutyl-P,P-diphenylphosphinous amide (13998-69-1)

Guidance literature:

With triethylamine; In tetrahydrofuran; at 0 - 25 ℃; for 3h; Inert atmosphere;

DOI:10.1002/ejic.202100232

Reference yield:

N,N-dibutyl-4-methylbenzenesulfonamide (599-65-5) + diphenylphosphide ion (34676-89-6) → N,N-dibutyl-P,P-diphenylphosphinous amide (13998-69-1)

Guidance literature:

In ammonia; for 0.116667h; Mechanism; Irradiation;

DOI:10.1002/poc.610080507

Reference yield:

→ N,N-dibutyl-P,P-diphenylphosphinous amide (13998-69-1)

Guidance literature:

Diphenylchlorophosphin, entspr. Amin;

upstream raw materials:

dibutylamine

chloro-diphenylphosphine

N,N-dibutyl-4-methylbenzenesulfonamide

diphenylphosphide ion

Downstream raw materials:

C₂₆H₃₃NP⁽¹⁺⁾*Br^(1-)

Refernces

• 1、 Adeyinka, Adedapo S.,Holzapfel, Cedric W.,Lamola, Jairus L.,Maumela, Munaka C.,Mmutlane, Edwin M.,Ngodwana, Lonwabo,Shilubana, Joy C.,Vatsha, Banele. "Easily Prepared Mono(N,N-dialkylamino)phosphine Palladium(II) Complexes: Structural and Catalytic Evaluation". supporting information. p. 2578 - 2582. Retrieved 2021/07/06.
• 2、 Cristau, Henri-Jean,Chene, Alain,Christol, Henri. "Synthesis of Aminophosphonium Salts by Arylation of Aminophosphines". . p. 551 - 554. Retrieved 2007/10/02.