2-Chlorooxirane

Base Information

• Chemical Name: 2-Chlorooxirane
• CAS No.: 7763-77-1
• Molecular Formula: C2H3ClO
• Molecular Weight: 78.4982
• DSSTox Substance ID: DTXSID10998848
• Nikkaji Number: J2.269A
• Wikidata: Q27109956
• Metabolomics Workbench ID: 54035
• Mol file: 7763-77-1.mol

Synonyms:2-chloroethylene oxide;chloroethylene oxide;chlorooxirane

Chemical Property of 2-Chlorooxirane

Chemical Property:

• Vapor Pressure: 83.9mmHg at 25°C
• Refractive Index: 1.3871 (estimate)
• Boiling Point: 83.5°C at 760 mmHg
• Flash Point: 15.7°C
• PSA: 12.53000
• Density: 1.3g/cm³
• LogP: 0.58150
• XLogP3: 0.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 77.9872424
• Heavy Atom Count: 4
• Complexity: 29.2

Purity/Quality:

99%, ^*data from raw suppliers

CHLOROETHYLENE OXIDE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1C(O1)Cl

Technology Process of 2-Chlorooxirane

There total 5 articles about 2-Chlorooxirane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

oxirane (75-21-8,99932-75-9) → 2-Chloro-oxirane (7763-77-1) + formaldehyd (50-00-0,30525-89-4,61233-19-0) + chloroethylene (75-01-4,9002-86-2) + acetyl chloride (75-36-5) + dimethylglyoxal (431-03-8) + 1,2:3,4-Diepoxybutane (564-00-1,1464-53-5,30031-64-2,30419-67-1,34897-03-5,298-18-0)

Guidance literature:

With chlorine; In gas; at 298 ℃; for 1.38889E-06h; under 1 Torr; Rate constant; Thermodynamic data; Product distribution; other reaction partner; energy data;

Reference yield:

oxirane (75-21-8,99932-75-9) → 2-Chloro-oxirane (7763-77-1)

Guidance literature:

With tert-butylhypochlorite; at 0 ℃; for 2h; Irradiation;

DOI:10.1021/ja00261a017

Reference yield:

oxirane (75-21-8,99932-75-9) → 2-Chloro-oxirane (7763-77-1) + 1,2-dichloroethylene oxide (60336-63-2) + formyl chloride (2565-30-2)

Guidance literature:

With chlorine; In gaseous matrix; at 23.9 ℃; for 0.00416667h; under 700 Torr; Irradiation;

DOI:10.1021/j100012a030

upstream raw materials:

oxirane

chloroethylene

Downstream raw materials:

4-chloro-1,3-dioxolan-2-one

N-7-(2-Oxoethyl)guanine

1-(3-Chlor-2-hydroxypropyl)-2-methyl-4,5-dinitroimidazol

C₈H₁₀ClNO

Refernces

• 1、 Chen, J.,Young V.,Hooshiyar, P. A.,Niki, H.,Hurley, M. D.. "FTIR Spectroscopic Study of the Cl-Atom-Initiated Reactions of Ethylene Oxide in O2/N2 Diluent". . p. 4071 - 4077. Retrieved 2007/10/02.
• 2、 Kesselmayer, Mark A.,Sheridan, Robert S.. "Methoxychlorocarbene. Matrix Spectroscopy and Photochemistry". . p. 99 - 107. Retrieved 2007/10/02.