<1,1'-Binaphthalene>-2,2'-diol dipropanoate

Base Information

• Chemical Name: <1,1'-Binaphthalene>-2,2'-diol dipropanoate
• CAS No.: 100465-49-4
• Molecular Formula: C₂₆H₂₂O₄
• Molecular Weight: 398.458
• Mol file: 100465-49-4.mol

Synonyms:<1,1'-Binaphthalene>-2,2'-diol dipropanoate

Chemical Property of <1,1'-Binaphthalene>-2,2'-diol dipropanoate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of <1,1'-Binaphthalene>-2,2'-diol dipropanoate

There total 1 articles about <1,1'-Binaphthalene>-2,2'-diol dipropanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

propionic acid anhydride (123-62-6) + 1,1'-bi-2-naphthol (602-09-5) → (S)-(1-(2-hydroxynapthalen-1-yl)napthalen-2-yl) propionate + <1,1'-Binaphthalene>-2,2'-diol dipropanoate (100465-49-4) + (R)-1,1'-Bi-2-naphthol (18531-94-7) + (S)-[1,1']-binaphthalenyl-2,2'-diol (18531-99-2) + (Ra)-propionic acid 2'-hydroxy[1,1']binaphthalen-2-yl ester

Guidance literature:

With (R)-(+)-2-phenyl-2,3-dihydrobenzo[d]imidazo[2,1-b]thiazole; In tert-Amyl alcohol; at 20 - 25 ℃; for 18h; regioselective reaction;

DOI:10.1002/chem.201805631

Reference yield:

<1,1'-Binaphthalene>-2,2'-diol dipropanoate (100465-49-4) → (R)-1,1'-Bi-2-naphthol (18531-94-7) + (S)-[1,1']-binaphthalenyl-2,2'-diol (18531-99-2)

Guidance literature:

With water; cholesterol esterase; In diethyl ether; at 25 ℃; Product distribution; catalyst activated by sodium taurocholate; pH = 7.00; rate of hydrolysis (relative to cholesterol acetate);

DOI:10.1021/ja00195a059

upstream raw materials:

propionic acid anhydride

1,1'-bi-2-naphthol

Downstream raw materials:

(R)-1,1'-Bi-2-naphthol

(S)-[1,1']-binaphthalenyl-2,2'-diol

Refernces