tetra-n-butylammonium tetrakis(pentafluorophenyl)borate

Base Information

• Chemical Name: tetra-n-butylammonium tetrakis(pentafluorophenyl)borate
• CAS No.: 136710-93-5
• Molecular Formula: C₁₆H₃₆N*C₂₄BF₂₀
• Molecular Weight: 921.512
• Mol file: 136710-93-5.mol

Synonyms:tetra-n-butylammonium tetrakis(pentafluorophenyl)borate

Chemical Property of tetra-n-butylammonium tetrakis(pentafluorophenyl)borate

Chemical Property:

Purity/Quality:

99.00% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tetra-n-butylammonium tetrakis(pentafluorophenyl)borate

There total 18 articles about tetra-n-butylammonium tetrakis(pentafluorophenyl)borate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

sodium tetrakis(pentafluorophenyl)borate-dimethoxyethane complex + tetrabutylammomium bromide (1643-19-2) → tetra-n-butylammonium tetrakis(pentafluorophenyl)borate (136710-93-5)

Guidance literature:

In water; at 20 ℃;

DOI:10.1002/anie.201100854

Reference yield: 99.0%

sodium tetrakis(pentafluorophenyl)-borate (2797-28-6) + tetrabutylammomium bromide (1643-19-2) → tetra-n-butylammonium tetrakis(pentafluorophenyl)borate (136710-93-5)

Guidance literature:

In water; Inert atmosphere;

DOI:10.1039/b910821a

Reference yield: 97.0%

lithium tetrakis(pentafluorophenyl)borate ethyl etherate (538369-97-0) + tetrabutyl-ammonium chloride (1112-67-0) → tetra-n-butylammonium tetrakis(pentafluorophenyl)borate (136710-93-5)

Guidance literature:

In dichloromethane;

DOI:10.1039/c2dt31622f

upstream raw materials:

bromopentafluorobenzene

tetrabutyl-ammonium chloride

tetrabutylammomium bromide

lithium tetrakis(pentafluorophenyl)borate

Refernces

• 1、 Lehrich, Steve W.,Hildebrandt, Alexander,Korb, Marcus,Lang, Heinrich. "From diferrocenyl-cyclopropenone to diferrocenyl-cyclopropenylium cations and triferrocenylpropenones: An electrochemical study". . p. 105 - 113. Retrieved 2017.
• 2、 Gericke, Henno J.,Barnard, Nicola I.,Erasmus, Elizabeth,Swarts, Jannie C.,Cook, Michael J.,Aquino, Manuel A.S.. "Solvent and electrolyte effects in enhancing the identification of intramolecular electronic communication in a multi redox-active diruthenium tetraferrocenoate complex, a triple-sandwiched dicadmium phthalocyanine and a ruthenocene-containing β-diketone". . p. 2222 - 2232. Retrieved 2010.
• 3、 Lawrence, Elliot J.,Oganesyan, Vasily S.,Wildgoose, Gregory G.,Ashley, Andrew E.. "Exploring the fate of the tris(pentafluorophenyl)borane radical anion in weakly coordinating solvents". . p. 782 - 789. Retrieved 2013.
• 4、 Zhou, Jiliang,Liu, Liu Leo,Cao, Levy L.,Stephan, Douglas W.. "A Phosphorus Lewis Super Acid: η5-Pentamethylcyclopentadienyl Phosphorus Dication". supporting information. p. 2699 - 2708. Retrieved 2018/11/30.