β-phenylseleno benzyl carbamate

Base Information

• Chemical Name: β-phenylseleno benzyl carbamate
• CAS No.: 106672-46-2
• Molecular Formula: C₂₄H₃₃NO₂Se
• Molecular Weight: 446.492
• Mol file: 106672-46-2.mol

Synonyms:β-phenylseleno benzyl carbamate

Chemical Property of β-phenylseleno benzyl carbamate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of β-phenylseleno benzyl carbamate

There total 3 articles about β-phenylseleno benzyl carbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

Phenylselenyl chloride (5707-04-0) + (E)-5-decene (7433-56-9) + O-benzyl carbamate (621-84-1) → β-phenylseleno benzyl carbamate (106672-46-2)

Guidance literature:

With silver tetrafluoroborate; In dichloromethane; at 25 ℃; for 6h;

DOI:10.1016/S0040-4039(00)84571-2

Reference yield: 76.0%

Phenylselenyl chloride (5707-04-0) + (E)-5-decene (7433-56-9) + O-benzyl carbamate (621-84-1) → erythro-benzyl <1-butyl-2-(phenylseleno)hexyl>carbamate (106672-46-2)

Guidance literature:

With silver tetrafluoroborate; In dichloromethane; at 25 ℃; for 6h; in the dark;

Reference yield: 73.0%

N-phenylselanylphthalimide (71098-88-9) + (E)-5-decene (7433-56-9) + O-benzyl carbamate (621-84-1) → erythro-benzyl <1-butyl-2-(phenylseleno)hexyl>carbamate (106672-46-2)

Guidance literature:

With tetrafluoroboric acid; In dichloromethane; at 40 - 45 ℃; for 8h;

upstream raw materials:

Phenylselenyl chloride

(E)-5-decene

O-benzyl carbamate

N-phenylselanylphthalimide

Downstream raw materials:

benzyl <(E)-1-butylhex-2-enyl>carbamate

Refernces

• 1、 Francisco, Cosme G.,Leon, Elisa I.,Salazar, Jose A.,Suarez, Ernesto. "AMINOSELENENYLATION OF OLEFINS. SYNTHESES OF β-PHENYLSELENO CARBAMATES". . p. 2513 - 2516. Retrieved 2007/10/02.