9,10-diphenylanthracene endoperoxide

Base Information

• Chemical Name: 9,10-diphenylanthracene endoperoxide
• CAS No.: 15257-17-7
• Molecular Formula: C26H18 O2
• Molecular Weight: 362.428
• Mol file: 15257-17-7.mol

Synonyms:Anthracene,9,10-diphenyl-, photooxide (6CI); 9,10-Diphenyl-9,10-epidioxyanthracene;9,10-Diphenylanthracene 9,10-endoperoxide; 9,10-Diphenylanthraceneendoperoxide; 9,10-Diphenylanthracene peroxide; NSC 255282

Chemical Property of 9,10-diphenylanthracene endoperoxide

Chemical Property:

• Vapor Pressure: 2.42E-08mmHg at 25°C
• Boiling Point: 463.9°Cat760mmHg
• Flash Point: 128.9°C
• PSA: 18.46000
• Density: 1.282g/cm³
• LogP: 5.54560

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 9,10-diphenylanthracene endoperoxide

There total 9 articles about 9,10-diphenylanthracene endoperoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

9,10-diphenylanthracene (1499-10-1) → 9,10-diphenyl-9,10-epidioxyanthracene (15257-17-7)

Guidance literature:

With oxygen; methylene blue; In dichloromethane; at -78 - 20 ℃; Irradiation;

DOI:10.1055/s-0031-1289764

Reference yield: 99.0%

9,10-diphenylanthracene (1499-10-1) → 9,10-diphenyl-9,10-dihydro-9,10-epidioxyanthracene (15257-17-7)

Guidance literature:

With oxygen; In toluene; at 20 ℃; for 7.5h; under 760.051 Torr; Irradiation;

DOI:10.1002/chem.201701300

Reference yield: 60.0%

1,3-diphenylisobenzofuran (5471-63-6) + 2,3-dibromobenzene (583-53-9) → 9,10-diphenylanthracene (1499-10-1) + 9,10-diphenyl-9,10-epidioxyanthracene (15257-17-7) + o-dibenzoylbenzene (1159-86-0)

Guidance literature:

With dihydrogen peroxide; lithium diphenylphosphide; In tetrahydrofuran; Product distribution; Mechanism; multistep reaction; possible intermediate formation of dehydrobenzene;

DOI:10.1039/P19830001697

upstream raw materials:

9,10-diphenylanthracene

1,3-diphenylisobenzofuran

2,3-dibromobenzene

carbon disulfide

Downstream raw materials:

9,10-phenanthrenequinone

2-Formyl-6-methoxy-4-methyl-benzoic acid methyl ester

9,10-diphenylanthracene

oxygen

Refernces

• 1、 Cambié, Dario,Zhao, Fang,Hessel, Volker,Debije, Michael G.,No?l, Timothy. "A Leaf-Inspired Luminescent Solar Concentrator for Energy-Efficient Continuous-Flow Photochemistry". . p. 1050 - 1054. Retrieved 2017.
• 2、 Martínez-Agramunt, Víctor,Peris, Eduardo. "Photocatalytic Properties of a Palladium Metallosquare with Encapsulated Fullerenes via Singlet Oxygen Generation". . p. 11836 - 11842. Retrieved 2019.
• 3、 Jing, Bingwen,Zhang, Manhua,Shen, Tao. "An unusual photosensitizer: Dyad of eosin-tris(2,2′-bipyridine)Ru(II)". . p. 3709 - 3711. Retrieved 2003.
• 4、 Zheng, Qinsi,Jockusch, Steffen,Zhou, Zhou,Blanchard, Scott C.. "The contribution of reactive oxygen species to the photobleaching of organic fluorophores". . p. 448 - 454. Retrieved 2014.
• 5、 Koenig, M.,Barrau, J.,Hamida, N. Ben. "Hydrotrioxydes organometalliques generateurs d'oxygene singulet". . p. 133 - 140. Retrieved 1988.
• 6、 Sun, Rui,Yang, Xiao,Ge, Yicen,Song, Jintong,Zheng, Xueli,Yuan, Maolin,Li, Ruixiang,Chen, Hua,Fu, Haiyan. "Visible-Light-Induced Oxazoline Formations fromN-Vinyl Amides Catalyzed by an Ion-Pair Charge-Transfer Complex". . p. 11762 - 11773. Retrieved 2021/09/28.
• 7、 Furuyama, Taniyuki,Miyaji, Yusuke,Maeda, Kazuya,Maeda, Hajime,Segi, Masahito. "Extremely Photostable Electron-Deficient Phthalocyanines that Generate High Levels of Singlet Oxygen". supporting information. p. 1678 - 1682. Retrieved 2019/01/04.