ethylamine; azide

Base Information

• Chemical Name: ethylamine; azide
• CAS No.: 87321-28-6
• Molecular Formula: C₂H₇N*HN₃
• Molecular Weight: 88.1123
• Mol file: 87321-28-6.mol

Synonyms:ethylamine; azide

Chemical Property of ethylamine; azide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of ethylamine; azide

There total 4 articles about ethylamine; azide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 3.0%

1-(N-Nitroso-N-ethylamino)ethyl acetate (58431-24-6) → ethanol (64-17-5) + ethylamine; azide (87321-28-6) + C4H9N5O

Guidance literature:

With sodium azide; at 25 ℃; Rate constant; 0.3 M cacodylic acid buffer (pH: 6.3), ionic strength 1 M (NaClO₄); also without aq. NaN₃ but in cacodylate-buffered D₂O;

DOI:10.1021/jo00113a007

Reference yield:

ethene (74-85-1) → methane (34557-54-5,27936-85-2) + methyl azide (624-90-8) + ethane (74-84-0) + ethylamine; azide (87321-28-6) + acetonitrile (75-05-8,26809-02-9) + ethyl azide (871-31-8)

Guidance literature:

With tris-(2-chloro-ethyl)-amine; In gas; at 30 ℃; Mechanism; Irradiation;

DOI:10.1246/bcsj.56.2363

Reference yield:

ethane (74-84-0) → methane (34557-54-5,27936-85-2) + methyl azide (624-90-8) + ethylamine; azide (87321-28-6) + methyl ammonium azide (87321-27-5) + acetonitrile (75-05-8,26809-02-9)

Guidance literature:

With tris-(2-chloro-ethyl)-amine; In gas; at 30 ℃; Mechanism; Irradiation;

DOI:10.1246/bcsj.56.2355

upstream raw materials:

propane

1-(N-Nitroso-N-ethylamino)ethyl acetate

ethane

ethene

Refernces

• 1、 Kodama, Sukeya. "Reactions of NH Radicals. V. Photolysis of HN3 in the Presence of C3H8 at 313 nm". . p. 2900 - 2910. Retrieved 2007/10/02.
• 2、 Kodama, Sukeya. "Reactions of NH Radicals. III. Photolysis of HN3 in the Presence of C2H4 at 313 nm". . p. 2363 - 2370. Retrieved 2007/10/02.