1-isothiocyanatoferrocene

Base Information

• Chemical Name: 1-isothiocyanatoferrocene
• CAS No.: 36472-46-5
• Molecular Formula: C₁₁H₉FeNS
• Molecular Weight: 243.112
• Mol file: 36472-46-5.mol

Synonyms:1-isothiocyanatoferrocene

Chemical Property of 1-isothiocyanatoferrocene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1-isothiocyanatoferrocene

There total 1 articles about 1-isothiocyanatoferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 32.0%

phosgene (75-44-5) + aminoferrocene (1273-82-1) → ferrocene (102-54-5,55404-68-7) + 1-isothiocyanatoferrocene (36472-46-5)

Guidance literature:

With carbon disulfide; ammonia; In toluene; byproducts: COS, NH4Cl, HCl; N2-atmosphere; bubbling dry NH3 (ice bath, 30 min), CS2 addn. (after 10 min of bubbling, pptn.), collection, dissoln. in THF, addn. of COCl2 in toluene (acetone/dry ice bath, 30 min), warming to room temp.; expelling excess COCl2 (N2-stream), evapn., extn. (Et2O), filtration, evapn., chromy. (SiO2, petroleum ether), distn. (bath temp. 85°C, 0.001 torr); elem. anal.;

upstream raw materials:

phosgene

aminoferrocene

Refernces