maltotriose peracetate

Base Information

• Chemical Name: maltotriose peracetate
• CAS No.: 76821-26-6
• Molecular Formula: C₄₀H₅₄O₂₇
• Molecular Weight: 966.853
• Hs Code.: 2940000080
• Mol file: 76821-26-6.mol

Synonyms:maltotriose peracetate

Chemical Property of maltotriose peracetate

Chemical Property:

Purity/Quality:

D-Maltotriose undecaacetate ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of maltotriose peracetate

There total 9 articles about maltotriose peracetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

maltotriose (6401-81-6,17659-52-8,19141-16-3,20702-55-0,52485-13-9,69429-19-2,80446-86-2,80446-87-3,94799-30-1,94799-74-3,113158-51-3,118396-93-3,121153-20-6,133267-59-1,1109-28-0,142185-35-1) + acetic anhydride (108-24-7) → maltotriose peracetate (76821-26-6)

Guidance literature:

With pyridine;

DOI:10.1016/j.carres.2008.04.035

Reference yield:

α-D-Glucopyranosyl-(1→4)-α-D-glucopyranosyl-(1→4)-β-D-glucopyranose (6401-81-6,17659-52-8,19141-16-3,20702-55-0,69429-19-2,80446-86-2,80446-87-3,94799-30-1,94799-74-3,113158-51-3,118396-93-3,121153-20-6,133267-59-1,142185-35-1,52485-13-9) + acetic anhydride (108-24-7) → (2S,3R,4S,5R,6R)-6-(acetoxymethyl)-5-((2R,3R,4S,5R,6R)-3,4-diacetoxy-6-(acetoxymethyl)-5-((2R,3R,4S,5R,6R)-3,4,5-triacetoxy-6-(acetoxymethyl)tetrahydro-2H-pyran-2-yloxy)tetrahydro-2H-pyran-2-yloxy)tetrahydro-2H-pyran-2,3,4-triyl triacetate (17690-94-7,31873-40-2,31873-41-3,35396-13-5,54192-78-8,61139-07-9,61687-84-1,61687-85-2,69349-75-3,76821-26-6,80446-83-9,113473-58-8,116182-08-2,139894-77-2,141847-33-8,151061-59-5,151061-60-8)

Guidance literature:

With sodium acetate; at 120 ℃; for 2h;

DOI:10.1016/S0008-6215(96)00331-X

Reference yield:

maltotriose (6401-81-6,17659-52-8,19141-16-3,20702-55-0,52485-13-9,69429-19-2,80446-86-2,80446-87-3,94799-30-1,94799-74-3,113158-51-3,118396-93-3,121153-20-6,133267-59-1,1109-28-0,142185-35-1) + acetic anhydride (108-24-7) → (2S,3R,4S,5R,6R)-6-(acetoxymethyl)-5-((2R,3R,4S,5R,6R)-3,4-diacetoxy-6-(acetoxymethyl)-5-((2R,3R,4S,5R,6R)-3,4,5-triacetoxy-6-(acetoxymethyl)tetrahydro-2H-pyran-2-yloxy)tetrahydro-2H-pyran-2-yloxy)tetrahydro-2H-pyran-2,3,4-triyl triacetate (17690-94-7,31873-40-2,31873-41-3,35396-13-5,54192-78-8,61139-07-9,61687-84-1,61687-85-2,69349-75-3,76821-26-6,80446-83-9,113473-58-8,116182-08-2,139894-77-2,141847-33-8,151061-59-5,151061-60-8)

Guidance literature:

With pyridine; at 20 ℃; for 8h;

DOI:10.1021/ja0693082

upstream raw materials:

maltotriose

acetic anhydride

α-D-Glucopyranosyl-(1→4)-α-D-glucopyranosyl-(1→4)-β-D-glucopyranose

maltotriose

Downstream raw materials:

m-formyl-p-hydroxy-benzyl-2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl-(1→4)-2,3,6-tri-O-acetyl-α-D-glucopyranosyl-(1→4)-2,3,6-tri-O-acetyl-1-thio-β-D-glucopyranoside

allyl O-(4,6-O-benzylidene-α-D-glucopyranosyl)-(1<*>4)-O-α-D-glucopyranosyl-(1<*>4)-β-D-glucopyranoside

N-benzyloxycarbonyl-1-amino-1-deoxyhexaethylene glycol 4-O-(4-O-(2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl)-2,3,6-tri-O-acetyl-α-D-glucopyranosyl)-2,3,6-tri-O-acetyl-β-D-glucopyranoside

Refernces

• 1、 Axer, Alexander,Jumde, Ravindra P.,Adam, Sebastian,Faust, Andreas,Sch?fers, Michael,Fobker, Manfred,Koehnke, Jesko,Hirsch, Anna K. H.,Gilmour, Ryan. "Enhancing glycan stabilityviasite-selective fluorination: modulating substrate orientation by molecular design". . p. 1286 - 1294. Retrieved 2021.
• 2、 Gowrishankar, Gayatri,Haywood, Tom,Sam Gambhir, Sanjiv,Steinberg, Idan,Zlitni, Aimen. "Maltotriose-based probes for fluorescence and photoacoustic imaging of bacterial infections". . . Retrieved 2020/03/19.
• 3、 Su, Yangqing,Meng, Lingkuan,Sun, Jiaqi,Li, Weijia,Shao, Liang,Chen, Kexuan,Zhou, Demin,Yang, Fan,Yu, Fei. "Design, synthesis of oleanolic acid-saccharide conjugates using click chemistry methodology and study of their anti-influenza activity". . . Retrieved 2019/08/20.