1-amino-2-phenoxy-4-anilinoanthraquinone

Base Information

• Chemical Name: 1-amino-2-phenoxy-4-anilinoanthraquinone
• CAS No.: 86397-46-8
• Molecular Formula: C₂₆H₁₈N₂O₃
• Molecular Weight: 406.441
• Mol file: 86397-46-8.mol

Synonyms:1-amino-2-phenoxy-4-anilinoanthraquinone

Chemical Property of 1-amino-2-phenoxy-4-anilinoanthraquinone

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-amino-2-phenoxy-4-anilinoanthraquinone

There total 3 articles about 1-amino-2-phenoxy-4-anilinoanthraquinone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-amino-2-bromo-4-phenylaminoanthraquinone (1564-71-2) + phenol (108-95-2,27073-41-2) → 1-amino-2-phenoxy-4-anilinoanthraquinone (86397-46-8)

Guidance literature:

With pyridine; potassium hydroxide; at 125 - 135 ℃; for 8h; Yield given;

DOI:10.1021/je00038a034

Reference yield:

1-amino-2, 4-dibromoanthraquinone (81-49-2) → 1-amino-2-phenoxy-4-anilinoanthraquinone (86397-46-8)

Guidance literature:

Multi-step reaction with 2 steps

1: 85.2 percent / copper carbonate, potassium acetate / 1 h / 130 - 140 °C

2: potassium hydroxide, pyridine / 8 h / 125 - 135 °C

With pyridine; potassium hydroxide; basic copper carbonate powder; potassium acetate;

DOI:10.1021/je00038a034

Reference yield:

aniline (62-53-3) → 1-amino-2-phenoxy-4-anilinoanthraquinone (86397-46-8)

Guidance literature:

Multi-step reaction with 2 steps

1: 85.2 percent / copper carbonate, potassium acetate / 1 h / 130 - 140 °C

2: potassium hydroxide, pyridine / 8 h / 125 - 135 °C

With pyridine; potassium hydroxide; basic copper carbonate powder; potassium acetate;

DOI:10.1021/je00038a034

upstream raw materials:

1-amino-2-bromo-4-phenylaminoanthraquinone

phenol

1-amino-2, 4-dibromoanthraquinone

aniline

Downstream raw materials:

1,4-dianilino-2-hydroxy-anthraquinone

1-Amino-9,10-dioxo-4-phenylamino-9,10-dihydroanthracen-2-carbonitril

1-amino-9,10-dioxo-4-phenylamino-9,10-dihydroanthracene-2,3-dicarbonitrile

1-[4-(2-Hydroxy-ethyl)-phenylamino]-2-phenoxy-4-phenylamino-anthraquinone

Refernces