NICKEL PHTHALOCYANINE

Base Information

• Chemical Name: NICKEL PHTHALOCYANINE
• CAS No.: 14055-02-8
• Molecular Formula: C32H16N8Ni
• Molecular Weight: 571.223
• Hs Code.: 29310099
• European Community (EC) Number: 237-893-3
• NSC Number: 40712
• DSSTox Substance ID: DTXSID401014783
• Mol file: 14055-02-8.mol

Synonyms:Nickel,[29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]-, (SP-4-1)-;Nickel,[phthalocyaninato(2-)]- (8CI);Phthalocyanine, nickel deriv. (6CI);29H,31H-Phthalocyanine, nickel complex;29H,31H-Phthalocyanine, nickel deriv.;NSC 173214;Nickel phthalocyanine;Nickel phthalocyanine blue;Nickel(2+)phthalocyaninate;Nickel(II) phthalocyanine;Phthalocyaninatonickel(II);[Phthalocyaninato(2-)]nickel;

Chemical Property of NICKEL PHTHALOCYANINE

Chemical Property:

• Appearance/Colour: very dark blue crystalline powder
• Melting Point: >300°C
• PSA: 69.16000
• LogP: 2.61600
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 570.085134
• Heavy Atom Count: 41
• Complexity: 983

Purity/Quality:

99% ^*data from raw suppliers

Nickel(II) phthalocyanine, min. 94% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T
• Hazard Codes: T
• Statements: 45-20/21/22
• Safety Statements: 53-36/37-45

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C2C(=C1)C3=NC4=NC(=NC5=C6C=CC=CC6=C([N-]5)N=C7C8=CC=CC=C8C(=N7)N=C2[N-]3)C9=CC=CC=C94.[Ni+2]

Technology Process of NICKEL PHTHALOCYANINE

There total 54 articles about NICKEL PHTHALOCYANINE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

nickel (7440-02-0) + phthalonitrile (91-15-6) → nickel(II) phthalocyanine (14055-02-8)

Guidance literature:

With sodium methylate; In methanol; pyrophoric Ni under water layer added to a methanol soln. containing an equivalent quantity of phthalonitrile and 5 drops of 30% soln of CH3ONa in methanol; flask maintained at 25°C for 24-72 h; blue product separated from unreacted metal by shaking and decanting with the solvent, washed with ethanol in Soxhlet equipment and dried in air; purity of 95-97%; elem. anal.;

DOI:10.1016/j.inoche.2004.10.006

Reference yield: 98.0%

nickel(II) acetate tetrahydrate (6018-89-9) + 29H,31H-Phthalocyanine (574-93-6) → nickel(II) phthalocyanine (14055-02-8)

Guidance literature:

With butyl(2-hydroxyethyl)dimethylammonium acetate; at 100 ℃; Ionic liquid; Inert atmosphere;

DOI:10.1080/00397911.2013.867505

Reference yield: 91.0%

phthalic anhydride (85-44-9) + nickel(II) chloride hexahydrate + urea (57-13-6) → nickel(II) phthalocyanine (14055-02-8)

Guidance literature:

With ammonium molybdate; at 130 ℃; for 0.0833333h; Microwave irradiation;

DOI:10.1142/S1088424612501106

upstream raw materials:

phthalonitrile

phthalimide

methanol

ethanol

Refernces

• 1、 Kharisov,Coronado, C.E. Cantú,Cerda, K.P. Coronado,Méndez, U. Ortiz,Guzmán, J.A. Jacobo,Patlán, L.A. Ramírez. "Use of elemental metals in different grade of activation for phthalocyanine preparation". . p. 1269 - 1272. Retrieved 2004.
• 2、 Yang, Chiu Her,Chang, Chau-ting. "Complexes derived from Phthalonitrile. The Intermediates to Nickel Phthalocyaninate". . p. 2539 - 2540. Retrieved 1982.
• 3、 Uchida, Hitoshi,Reddy, Paidi Yella,Nakamura, Shuichi,Toru, Takeshi. "Novel Efficient Preparative Method for Phthalocyanines from Phthalimides and Phthalic Anhydride with HMDS". . p. 8736 - 8738. Retrieved 2003.
• 4、 Kopylovich, Maximilian N.,Kukushkin, Vadim Yu.,Haukka, Matti,Luzyanin, Konstantin V.,Pombeiro, Armando J. L.. "An efficient synthesis of phthalocyanines based on an unprecedented double-addition of oximes to phthalonitriles". . p. 15040 - 15041. Retrieved 2004.
• 5、 Br?uer, Bj?rn,Vaynzof, Yana,Zhao, Wei,Kahn, Antoine,Li, Wen,Zahn, Dietrich R.T.,De Julián Fernández, César,Sangregorio, Claudio,Salvan, Georgeta. "Electronic and magnetic properties of Ni nanoparticles embedded in various organic semiconductor matrices". . p. 4565 - 4570. Retrieved 2009.
• 6、 Day, P.,Williams, R. J. P.. "". . p. 567 - 570. Retrieved 1962.
• 7、 Tan, Amin,Tian, Min,Yang, Yan,Zhang, Gai,Zhang, Yufan. "Effects of MN4-Type Coordination Structure in Metallophthalocyanine for Bio-Inspired Oxidative Desulfurization Performance". . . Retrieved 2022/02/14.
• 8、 Denekamp, Ilse M.,Veenstra, Florentine L.P.,Jungbacker, Peter,Rothenberg, Gadi. "A simple synthesis of symmetric phthalocyanines and their respective perfluoro and transition-metal complexes". . . Retrieved 2019/03/23.