Salicylaldehyde imine

Base Information

• Chemical Name: Salicylaldehyde imine
• CAS No.: 3117-61-1
• Molecular Formula: C7H7 N O
• Molecular Weight: 121.139
• NSC Number: 92396
• DSSTox Substance ID: DTXSID00418888
• Nikkaji Number: J2.265.024F,J2.265.025D,J247.774B
• Wikidata: Q27124287
• Metabolomics Workbench ID: 58826
• Mol file: 3117-61-1.mol

Synonyms:salicylaldehyde imine;salicylaldimine;salicylideneamine;2-methanimidoylphenol;3117-61-1;salicylideneimine;2-(iminomethyl)phenol;NSC92396;2-Oxylatobenzylideneiminium;SCHEMBL49998;CHEBI:55426;DTXSID00418888;NSC-92396;AKOS006349237;6-(Aminomethylene)-1,3-cyclohexadiene-5-one;Q27124287

Chemical Property of Salicylaldehyde imine

Chemical Property:

• Vapor Pressure: 0.0384mmHg at 25°C
• Boiling Point: 240.2°C at 760 mmHg
• Flash Point: 99.1°C
• PSA: 44.08000
• Density: 1.289g/cm³
• LogP: 1.48960
• XLogP3: 1.3
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 1
• Exact Mass: 121.052763847
• Heavy Atom Count: 9
• Complexity: 103

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C(=C1)C=N)O

Technology Process of Salicylaldehyde imine

There total 3 articles about Salicylaldehyde imine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

salicylaldehyde (90-02-8) → 2-(iminomethyl)phenol (3117-61-1)

Guidance literature:

With ammonia; In ethanol; for 2h;

DOI:10.1039/DT9860001623

Reference yield:

[Ni(OC6H4CHNC6H5)2] (38929-70-3,14266-60-5) + ammonium chloride → 2-(iminomethyl)phenol (3117-61-1) + nickel(II) (14701-22-5)

Guidance literature:

In methanol; byproducts: C6H5NH2;

DOI:10.1016/S0020-1693(00)83239-9

Reference yield:

→ 2-(iminomethyl)phenol (3117-61-1)

Guidance literature:

Oxim 1a, h*ν;

DOI:10.1016/S0040-4039(01)93215-0

upstream raw materials:

salicylaldehyde

[Ni(OC₆H₄CHNC₆H₅)2]

Downstream raw materials:

salicylaldiminepropyltriethoxysilane

bis(N-salicylaldimino) Co(II)

Refernces

• 1、 Yuan, Lai Sin,Chandren, Sheela,Efendi, Jon,Ho, Chin Siong,Nur, Hadi. "Hydrophobic effect of silica functionalized with silylated Ti-salicylaldimine complex on limonene oxidation by aqueous hydrogen peroxide". . p. 1905 - 1917. Retrieved 2015/12/30.
• 2、 Mazzi, Ulderico,Refosco, Fiorenzo,Tisato, Francesco,Bandoli, Giuliano,Nicolini, Marino. "Mixed Tri- and Bi-dentate Schiff-base Complexes of Technetium(V) and Rhenium(V). The Crystal Structure of N-(2-Oxidophenyl)salicylideneiminato-NOO')oxo(8-quinolinolato-NO)technetium(V)". . p. 1623 - 1628. Retrieved 2007/10/02.