p-Toluol-(-N-carbethoxy)-iminosulfonsaeurechlorid

Base Information

• Chemical Name: p-Toluol-(-N-carbethoxy)-iminosulfonsaeurechlorid
• CAS No.: 93506-31-1
• Molecular Formula: C₁₀H₁₂ClNO₃S
• Molecular Weight: 261.729
• Mol file: 93506-31-1.mol

Synonyms:p-Toluol-(-N-carbethoxy)-iminosulfonsaeurechlorid

Chemical Property of p-Toluol-(-N-carbethoxy)-iminosulfonsaeurechlorid

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of p-Toluol-(-N-carbethoxy)-iminosulfonsaeurechlorid

There total 6 articles about p-Toluol-(-N-carbethoxy)-iminosulfonsaeurechlorid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

sodium 4-methylbenzenesulfinate (824-79-3) → p-Toluol-(-N-carbethoxy)-iminosulfonsaeurechlorid (93506-31-1)

Guidance literature:

Multi-step reaction with 4 steps

1.1: thionyl chloride / dichloromethane / 3 h / 0 - 20 °C

2.1: triethylamine / 20 °C

3.1: lithium hexamethyldisilazane / tetrahydrofuran / -78 °C

3.2: 20 °C

4.1: N-chloro-succinimide / 2 h / 20 °C

With N-chloro-succinimide; thionyl chloride; triethylamine; lithium hexamethyldisilazane; In tetrahydrofuran; dichloromethane;

DOI:10.1021/acsmedchemlett.9b00285

Reference yield:

4-methylbenzenesulfinyl chloride (10439-23-3) → p-Toluol-(-N-carbethoxy)-iminosulfonsaeurechlorid (93506-31-1)

Guidance literature:

Multi-step reaction with 3 steps

1.1: triethylamine / 20 °C

2.1: lithium hexamethyldisilazane / tetrahydrofuran / -78 °C

2.2: 20 °C

3.1: N-chloro-succinimide / 2 h / 20 °C

With N-chloro-succinimide; triethylamine; lithium hexamethyldisilazane; In tetrahydrofuran;

DOI:10.1021/acsmedchemlett.9b00285

Reference yield:

p-tolylsulfinyl amide (6873-55-8) → p-Toluol-(-N-carbethoxy)-iminosulfonsaeurechlorid (93506-31-1)

Guidance literature:

With N-chloro-succinimide; at 20 ℃; for 2h;

DOI:10.1021/acsmedchemlett.9b00285

upstream raw materials:

4-methylbenzenesulfinyl chloride

sodium chloro(ethoxycarbonyl)chloroamide

sodium 4-methylbenzenesulfinate

methyl p-toluene sulfinate

Downstream raw materials:

4-(p-tolylsulfonimidoyl)morpholine

Tosylurethane

Refernces