2-(Trimethylammonio)ethyl methacrylate chloride

Base Information

• Chemical Name: 2-(Trimethylammonio)ethyl methacrylate chloride
• CAS No.: 5039-78-1
• Deprecated CAS: 114266-87-4,115506-29-1,57619-92-8,68389-22-0,77901-66-7,80464-37-5,81489-33-0,92717-86-7,99581-72-3,99913-33-4,161445-29-0,313057-69-1,732285-71-1,1008528-87-7,1217193-20-8,1411052-00-0,1633768-03-2,1639819-38-7,1899905-86-2,2098238-87-8,2135358-41-5,73032-93-6,2111952-14-6,2489374-75-4,2640471-50-5,161107-49-9,34031-58-8,60005-84-7,78474-69-8,86697-72-5,94947-95-2,189767-71-3,257881-49-5,811433-18-8,87435-56-1,158395-56-3,1620586-48-2,2098283-80-6,81444-26-0,1851326-16-3,1008528-87-7,115506-29-1,1217193-20-8,1411052-00-0,161445-29-0,1639819-38-7,313057-69-1,57619-92-8,68389-22-0,73032-93-6,77901-66-7,80464-37-5,81489-33-0,92717-86-7,99581-72-3,99913-33-4
• Molecular Formula: C9H18NO2^.Cl
• Molecular Weight: 207.7
• Hs Code.: 29239000
• European Community (EC) Number: 225-733-5,607-876-9
• UNII: PP88R88K3O
• DSSTox Substance ID: DTXSID3027586
• Wikidata: Q27286691
• RXCUI: 1314234,1370678,1372481,1372567
• ChEMBL ID: CHEMBL3187310
• Mol file: 5039-78-1.mol

Synonyms:(2-(methacryloyloxy)ethyl)trimethyl ammonium chloride;(2-(methacryloyloxy)ethyl)trimethylammonium;(2-(methacryloyloxy)ethyl)trimethylammonium chloride;(2-methacryloyloxyethyl) trimethyl ammonium chloride;2-(trimethylammonio)ethyl methacrylate;2-methacryloxyethyl trimethyl ammonium chloride;2-methacyloyloxyethyltrimethyl ammonium chloride;MAETAC cpd;MAETAC monomer;METAC cpd;methacryloyl ethyl trimethyl ammonium chloride;TMAEM

Chemical Property of 2-(Trimethylammonio)ethyl methacrylate chloride

Chemical Property:

• Appearance/Colour: aqueous solution
• Melting Point: -25°C
• Refractive Index: n20/D 1.469
• Boiling Point: >100°C
• Flash Point: >100°C
• PSA: 26.30000
• Density: 1.105
• LogP: -2.18410
• Storage Temp.: Inert atmosphere,Room Temperature
• Water Solubility.: It is soluble in water.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 5
• Exact Mass: 207.1026065
• Heavy Atom Count: 13
• Complexity: 180

Purity/Quality:

78%min ^*data from raw suppliers

[2-(Methacryloyloxy)ethyl]trimethylammoniumChloride,72%solutioninH2O,stabilized ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn
• Hazard Codes: Xn,Xi
• Statements: 22-36/38-43-36
• Safety Statements: 26-36-36/37-24/25

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=C)C(=O)OCC[N+](C)(C)C.[Cl-]
• Uses: 2-(Methacryloyloxy)ethyltrimethylammonium chloride is a zirconium, aluminum and organic surface treated multipurpose rutile titanium dioxide pigment, it has narrow-size material distribution, good whiteness and high weather resistance. It is widely used in coating, plastics, paints, rubber and ink production, leather, cosmetics, soaps, plastics and in paper industry.

Technology Process of 2-(Trimethylammonio)ethyl methacrylate chloride

There total 1 articles about 2-(Trimethylammonio)ethyl methacrylate chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

methylene chloride (74-87-3) + 2-(dimethylamino)ethyl methacrylate (2867-47-2) → [2-(methacryloyloxy)ethyl]trimethylammonium chloride (5039-78-1)

Guidance literature:

In acetone;

DOI:10.1023/A:1026318630534

Reference yield:

[2-(methacryloyloxy)ethyl]trimethylammonium chloride (5039-78-1) → choline chloride (67-48-1)

Guidance literature:

Multi-step reaction with 2 steps

1: triethylamine / acetonitrile / 72 h / 26.84 °C

2: sodium hydroxide / water / 6 h / 59.84 °C

With triethylamine; sodium hydroxide; In water; acetonitrile; 1: |Michael Addition;

DOI:10.1039/d1gc01525g

Reference yield:

decylthiol (143-10-2) + [2-(methacryloyloxy)ethyl]trimethylammonium chloride (5039-78-1) → choline chloride (67-48-1) + C14H28O2S

Guidance literature:

Multi-step reaction with 2 steps

1: triethylamine / acetonitrile / 72 h / 26.84 °C

2: sodium hydroxide / water / 6 h / 59.84 °C

With triethylamine; sodium hydroxide; In water; acetonitrile; 1: |Michael Addition;

DOI:10.1039/d1gc01525g

upstream raw materials:

methylene chloride

2-(dimethylamino)ethyl methacrylate

Downstream raw materials:

[2-(methacryloyloxy)ethyl]trimethylammonium p-dodecylbenzenesulfonate

poly( N,N,N-trimethyl-2-[(2-methyl-1-oxo-2-propenyl)oxy] ethanaminium chloride-co-2-propeneamide)

choline chloride

3-(Dodecylthio)-2-methylpropanoic Acid

Refernces

• 1、 Kuznetsova,Kazantsev,Shirshin,Khokhlova,Malyshev. "Hydrolysis of N,N-dimethylaminoethyl methacrylate and its salts in concentrated aqueous solutions". . p. 1117 - 1120. Retrieved 2007/10/03.