13β-phenyl-11,13-dihydroparthenin

Base Information

• Chemical Name: 13β-phenyl-11,13-dihydroparthenin
• CAS No.: 1426162-39-1
• Molecular Formula: C₂₁H₂₄O₄
• Molecular Weight: 340.419
• Mol file: 1426162-39-1.mol

Synonyms:13β-phenyl-11,13-dihydroparthenin

Chemical Property of 13β-phenyl-11,13-dihydroparthenin

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of 13β-phenyl-11,13-dihydroparthenin

There total 1 articles about 13β-phenyl-11,13-dihydroparthenin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

parthenin (508-59-8,20555-04-8,69401-55-4,69401-56-5,93665-22-6) + phenylmagnesium bromide (100-58-3) → 13β-phenyl-11,13-dihydroparthenin (1426162-39-1) + 13α-phenyl-11,13-dihydroparthenin (1426162-48-2)

Guidance literature:

phenylmagnesium bromide; With copper(l) iodide; (R)-1,1'-Bi-2-naphthol; In tetrahydrofuran; toluene; at -78 ℃; for 0.0833333h; Inert atmosphere;

parthenin; In tetrahydrofuran; toluene; at -78 ℃; for 4h; Overall yield = 68 %; diastereoselective reaction; Inert atmosphere;

DOI:10.1016/j.tetlet.2012.12.043

upstream raw materials:

parthenin

phenylmagnesium bromide

Refernces