POTASSIUM HEXYLXANTHATE

Base Information

• Chemical Name: POTASSIUM HEXYLXANTHATE
• CAS No.: 2720-76-5
• Molecular Formula: C7H14 O S2 . K
• Molecular Weight: 216.41
• Mol file: 2720-76-5.mol

Synonyms:Carbonicacid, dithio-, O-hexyl ester, potassium salt (8CI); Carbonodithioic acid,O-hexyl ester, potassium salt (9CI); Xanthic acid, hexyl-, potassium salt(7CI); Hexylpotassium xanthogenate; Potassium O-hexylxanthate; Potassium hexylxanthate

Chemical Property of POTASSIUM HEXYLXANTHATE

Chemical Property:

• Vapor Pressure: 0.261mmHg at 25°C
• Boiling Point: 211.7°C at 760 mmHg
• Flash Point: 81.9°C
• PSA: 41.32000
• LogP: 2.41510

Purity/Quality:

98%Min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of POTASSIUM HEXYLXANTHATE

There total 3 articles about POTASSIUM HEXYLXANTHATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.8%

→ potassium-O-hexan-1-yl-dithiocarbonate (2720-76-5)

Guidance literature:

With potassium hydroxide; In tetrahydrofuran; at 5 - 20 ℃; for 3.33333h;

Reference yield: 77.28%

carbon disulfide (75-15-0,12122-00-8) + hexan-1-ol (111-27-3) → potassium-O-hexan-1-yl-dithiocarbonate (2720-76-5)

Guidance literature:

hexan-1-ol; With potassium hydroxide; for 4h; Schlenk technique; Inert atmosphere;

carbon disulfide; Schlenk technique; Inert atmosphere;

DOI:10.1021/acs.inorgchem.1c01110

Reference yield:

hexan-1-ol (111-27-3) → potassium-O-hexan-1-yl-dithiocarbonate (2720-76-5)

Guidance literature:

With potassium hydroxide; at 25 ℃;

upstream raw materials:

hexan-1-ol

carbon disulfide

Downstream raw materials:

carbon disulfide

hexan-1-ol

O-Hexyl-S-(4-brom-phenacyl)-dithiocarbonat

Refernces

• 1、 Bakly, Ali A.K.,Collison, David,Ahumada-Lazo, Ruben,Binks, David J.,Smith, Matthew,Raftery, James,Whitehead, George F. S.,O'Brien, Paul,Lewis, David J.. "Synthesis, X-ray Single-Crystal Structural Characterization, and Thermal Analysis of Bis(O-alkylxanthato)Cd(II) and Bis(O-alkylxanthato)Zn(II) Complexes Used as Precursors for Cadmium and Zinc Sulfide Thin Films". supporting information. p. 7573 - 7583. Retrieved 2021/05/26.
• 2、 Lewis, Edward A.,McNaughter, Paul D.,Yin, Zhongjie,Chen, Yiqiang,Brent, Jack R.,Saah, Selina A.,Raftery, James,Awudza, Johannes A. M.,Malik, M. Azad,Obrien, Paul,Haigh, Sarah J.. "In situ synthesis of pbs nanocrystals in polymer thin films from lead(II) xanthate and dithiocarbamate complexes: Evidence for size and morphology control". . p. 2127 - 2136. Retrieved 2015/04/14.