Benzhydryl acetate

Base Information

• Chemical Name: Benzhydryl acetate
• CAS No.: 954-67-6
• Molecular Formula: C15H14O2
• Molecular Weight: 226.275
• European Community (EC) Number: 653-152-0
• NSC Number: 120238
• DSSTox Substance ID: DTXSID90914026
• Nikkaji Number: J260.942H
• Wikidata: Q63398881
• Mol file: 954-67-6.mol

Synonyms:Benzhydryl acetate;DIPHENYLMETHYL ACETATE;954-67-6;Benzhydryl acetate #;SCHEMBL1202828;DTXSID90914026;NSC120238;AKOS024323813;NSC-120238;97275-25-7;Benzenemethanol, .alpha.-phenyl-, acetate;Q63398881

Chemical Property of Benzhydryl acetate

Chemical Property:

• Vapor Pressure: 0.000421mmHg at 25°C
• Boiling Point: 316°C at 760 mmHg
• Flash Point: 127.6°C
• Density: 1.097g/cm³
• XLogP3: 3.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 4
• Exact Mass: 226.099379685
• Heavy Atom Count: 17
• Complexity: 219

Purity/Quality:

98%min ^*data from raw suppliers

BENZHYDRYL ACETATE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CC(=O)OC(C1=CC=CC=C1)C2=CC=CC=C2

Technology Process of Benzhydryl acetate

There total 100 articles about Benzhydryl acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

1,1-Diphenylmethanol (91-01-0) → benzhydryl acetate (954-67-6) + diphenylchloromethane (90-99-3)

Guidance literature:

With acetyl chloride; In dichloromethane; Yields of byproduct given; 1.) 0 deg C, 2.) room temperature, 1 h;

DOI:10.1016/S0040-4020(01)80747-X

Reference yield: 91.0%

1,1-Diphenylmethanol (91-01-0) + acetyl chloride (75-36-5) → benzhydryl acetate (954-67-6) + diphenylchloromethane (90-99-3)

Guidance literature:

In dichloromethane; Yield given; 1.) 0 deg C, 2.) room temperature, 1 h;

DOI:10.1016/S0040-4020(01)80747-X

Reference yield: 91.0%

1,1-Diphenylmethanol (91-01-0) + acetic anhydride (108-24-7) → benzhydryl acetate (954-67-6) + acetic acid (64-19-7,77671-22-8)

Guidance literature:

With 3-((3-(trisilyloxy)propyl)propionamide)-1-methylimidazolium chloride ionic liquid supported on magnetic nanoparticle Fe₂O₃; at 20 ℃; for 3h;

DOI:10.1016/j.jmmm.2015.10.044

upstream raw materials:

methyl magnesium iodide

1,1-Diphenylmethanol

diethyl ether

sodium acetate

Downstream raw materials:

ethane

3-methylpentan-3-ol

benzhydryl ether

ethene

Refernces

• 1、 Liu, Wenbin,Twilton, Jack,Wei, Bo,Lee, Maizie,Hopkins, Melissa N.,Bacsa, John,Stahl, Shannon S.,Davies, Huw M. L.. "Copper-Catalyzed Oxidation of Hydrazones to Diazo Compounds Using Oxygen as the Terminal Oxidant". . p. 2676 - 2683. Retrieved 2021/03/03.
• 2、 Chen, Jyun-Siao,Huang, Po-Hsun,Hsieh, Ya-Chi,Liu, Jen-Wei,Hsu, Hsiao-Lin,Zhang, Kai-Min,Wu, Ren-Tsung,Chang, Ting-Shuo,Liu, Yu-Hao,Wu, Hsin-Ru,Luo, Shun-Yuan. "Trimethylsilyl Esters as Novel Dual-Purpose Protecting Reagents". supporting information. p. 754 - 762. Retrieved 2021/12/02.