1-(2,4-Dinitrophenyl)-2-[1-(naphthalen-1-yl)ethylidene]hydrazine

Base Information

• Chemical Name: 1-(2,4-Dinitrophenyl)-2-[1-(naphthalen-1-yl)ethylidene]hydrazine
• CAS No.: 5471-15-8
• Molecular Formula: C18H14 N4 O4
• Molecular Weight: 350.334
• Hs Code.: 2928000090
• NSC Number: 26091
• Mol file: 5471-15-8.mol

Synonyms:1-(2,4-dinitrophenyl)-2-[1-(naphthalen-1-yl)ethylidene]hydrazine;5471-15-8;N-[(E)-1-naphthalen-1-ylethylideneamino]-2,4-dinitroaniline;NSC26091;NSC-26091;AKOS001012102;Z49554961

Chemical Property of 1-(2,4-Dinitrophenyl)-2-[1-(naphthalen-1-yl)ethylidene]hydrazine

Chemical Property:

• Vapor Pressure: 1.1E-11mmHg at 25°C
• Boiling Point: 539°Cat760mmHg
• Flash Point: 279.8°C
• PSA: 116.03000
• Density: 1.36g/cm³
• LogP: 5.61170
• XLogP3: 6
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 3
• Exact Mass: 350.10150494
• Heavy Atom Count: 26
• Complexity: 556

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=NNC1=C(C=C(C=C1)[N+](=O)[O-])[N+](=O)[O-])C2=CC=CC3=CC=CC=C32
• Isomeric SMILES: C/C(=N\NC1=C(C=C(C=C1)[N+](=O)[O-])[N+](=O)[O-])/C2=CC=CC3=CC=CC=C32

Technology Process of 1-(2,4-Dinitrophenyl)-2-[1-(naphthalen-1-yl)ethylidene]hydrazine

There total 3 articles about 1-(2,4-Dinitrophenyl)-2-[1-(naphthalen-1-yl)ethylidene]hydrazine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

(S)-1-(1-Naphthyl)ethanol (15914-84-8,1517-72-2) + (2,4-dinitro-phenyl)-hydrazine (119-26-6) → 1-acetonaphthone 2,4-dinitrophenylhydrazone (5471-15-8)

Guidance literature:

(S)-1-(1-Naphthyl)ethanol; With peracetic acid; C₉H₁₇NO₅S^(1-)*C₁₂H₁₁IN⁽¹⁺⁾; acetic acid; In 1,1,1,3',3',3'-hexafluoro-propanol; at 20 ℃; for 18h;

(2,4-dinitro-phenyl)-hydrazine; With sulfuric acid; In diethyl ether; ethanol; water;

DOI:10.1016/j.tetlet.2012.01.053

Reference yield:

naphthalene (91-20-3,71998-51-1,72931-45-4) → 1-acetonaphthone 2,4-dinitrophenylhydrazone (5471-15-8)

Guidance literature:

Multi-step reaction with 2 steps

1: carbon disulfide; AlCl₃

With carbon disulfide; aluminium trichloride;

DOI:10.1021/ja01267a061

Reference yield:

1'-naphthacetophenone (941-98-0) + (2,4-dinitro-phenyl)-hydrazine (119-26-6) → 1-acetonaphthone 2,4-dinitrophenylhydrazone (5471-15-8)

Guidance literature:

DOI:10.1021/ja01267a061

upstream raw materials:

1'-naphthacetophenone

(2,4-dinitro-phenyl)-hydrazine

naphthalene

(S)-1-(1-Naphthyl)ethanol

Refernces