4-Nitrobenzonitrile radical anion

Base Information

• Chemical Name: 4-Nitrobenzonitrile radical anion
• CAS No.: 12402-47-0
• Molecular Formula: C₇H₄N₂O₂
• Molecular Weight: 148.121
• Mol file: 12402-47-0.mol

Synonyms:4-Nitrobenzonitrile radical anion

Chemical Property of 4-Nitrobenzonitrile radical anion

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4-Nitrobenzonitrile radical anion

There total 22 articles about 4-Nitrobenzonitrile radical anion which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C8H7N2O3 (91948-76-4) → formaldehyd (50-00-0,30525-89-4,61233-19-0) + 4-Nitrobenzonitrile radical anion (12402-47-0)

Guidance literature:

In water; at 19.9 ℃; Rate constant; pH = 4 - 5;

Reference yield:

1,4-dicyanobenzene anion radical (623-26-7) + 4-nitrobenzonitrile (619-72-7) → terephthalonitrile (623-26-7) + 4-Nitrobenzonitrile radical anion (12402-47-0)

Guidance literature:

at 150 ℃; Rate constant; Thermodynamic data; ΔG⁰;

DOI:10.1021/ja00278a014

Reference yield:

C12H15N2O3 → pivalaldehyde (630-19-3) + 4-Nitrobenzonitrile radical anion (12402-47-0)

Guidance literature:

In water; at 20 ℃; Rate constant; Thermodynamic data; ΔH⁺⁺, ΔS⁺⁺;

DOI:10.1021/ja00334a015

upstream raw materials:

ethanol radical

4-nitrobenzonitrile

2-hydroxy-2-propyl radical

Downstream raw materials:

p-Dinitrobenzol-Monoradikalanion

4-nitrobenzonitrile

p-benzosemiquinone radical anion

1,4-naphthoquinone anion radical

Refernces

• 1、 Stevenson, Gerald R.,Sedgwick, James B.,Reiter, Richard C.. "Kinetic Parameters for Hydrogen Bonding to an Anion Radical". . p. 1347 - 1350. Retrieved 1984.
• 2、 Ferry, John L.,Glaze, William H.. "Photocatalytic reduction of nitroorganics over illuminated titanium dioxide: Electron transfer between excited-state TiO2 and nitroaromatics". . p. 2239 - 2244. Retrieved 2007/10/03.
• 3、 Jagannadham, V.,Steenken, S.. "Heterolysis of o-(α-Hydroxyalkyl)-4-cyanophenyl Nitrite: Simultaneous Polar and Steric Effects". . p. 907 - 908. Retrieved 2007/10/02.