1-AsPh₂-2-SHC₆H₄

Base Information

• Chemical Name: 1-AsPh₂-2-SHC₆H₄
• CAS No.: 16823-73-7
• Molecular Formula: C₁₈H₁₅AsS
• Molecular Weight: 338.305
• Mol file: 16823-73-7.mol

Synonyms:1-AsPh₂-2-SHC₆H₄

Chemical Property of 1-AsPh₂-2-SHC₆H₄

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of 1-AsPh₂-2-SHC₆H₄

There total 5 articles about 1-AsPh₂-2-SHC₆H₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

chlorodiphenylarsine (712-48-1) + Lithium 2-lithiobenzenethiolate (117526-82-6) → 1-AsPh2-2-SHC6H4 (16823-73-7)

Guidance literature:

chlorodiphenylarsine; Lithium 2-lithiobenzenethiolate; In tetrahydrofuran; at -78 - 20 ℃;

With sulfuric acid; at 0 ℃; pH=3 - 4;

DOI:10.1021/ic300002p

Reference yield:

(2-bromophenyl)diphenylarsine (57170-67-9) → 1-AsPh2-2-SHC6H4 (16823-73-7)

Guidance literature:

Multistep reaction; (i) nBuLi, (ii) sulfur;

DOI:10.1039/j19670001277

Reference yield:

o-Bromphenylarsindichlorid (57170-65-7) → 1-AsPh2-2-SHC6H4 (16823-73-7)

Guidance literature:

Multi-step reaction with 2 steps

2: (i) nBuLi, (ii) sulfur

DOI:10.1039/j19670001277

upstream raw materials:

(2-bromophenyl)diphenylarsine

o-Bromphenylarsindichlorid

2-bromoaniline

chlorodiphenylarsine

Downstream raw materials:

C₃₈H₃₂As₂S₂

cis-[Pt((1-AsPh2-2-SHC6H4)-κ2S,As)2]

trans-[Ni((1-AsPh2-2-SHC6H4)-κ2S,As)2]

Ga(t)Bu((SC6H4-2-AsPh2)-κ2S,As)((SC6H4-2-AsPh2)-κS)

Refernces