perbenzoyl p-nitrophenyl carbonate

Base Information

• Chemical Name: perbenzoyl p-nitrophenyl carbonate
• CAS No.: 42464-09-5
• Molecular Formula: C₁₄H₉NO₇
• Molecular Weight: 303.228
• Mol file: 42464-09-5.mol

Synonyms:perbenzoyl p-nitrophenyl carbonate

Chemical Property of perbenzoyl p-nitrophenyl carbonate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of perbenzoyl p-nitrophenyl carbonate

There total 1 articles about perbenzoyl p-nitrophenyl carbonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

Perbenzoic acid (93-59-4) + 4-Nitrophenyl chloroformate (7693-46-1) → perbenzoyl p-nitrophenyl carbonate (42464-09-5)

Guidance literature:

With pyridine; In dichloromethane; at -15 ℃; for 0.5h;

DOI:10.1021/ja00405a043

Reference yield: 60.0%

perbenzoyl p-nitrophenyl carbonate (42464-09-5) + methoxybenzene (100-66-3) → 4-nitro-phenol (100-02-7,78813-13-5,89830-32-0) + 4-methoxylbiphenyl (613-37-6) + 2-methoxy-1,1'-biphenyl (86-26-0,292625-97-9) + 3-methoxybiphenyl (2113-56-6)

Guidance literature:

at 180 ℃; for 5h; Further byproducts given;

DOI:10.1021/ja00405a043

Reference yield: 40.0%

perbenzoyl p-nitrophenyl carbonate (42464-09-5) + methoxybenzene (100-66-3) → 4-nitro-phenol (100-02-7,78813-13-5,89830-32-0) + 4-methoxyphenyl benzoate (1523-19-9) + 2-methoxyphenyl benzoate (531-37-3) + 4-methoxy-phenol (150-76-5) + 2-methoxy-phenol (90-05-1) + benzoic acid (65-85-0,8013-63-6)

Guidance literature:

With trifluoroacetic acid; at 70 ℃; for 60h; Product distribution; Mechanism; influence of temperature, reagent;

DOI:10.1021/ja00405a043

upstream raw materials:

Perbenzoic acid

4-Nitrophenyl chloroformate

Downstream raw materials:

4-nitro-phenol

4-methoxylbiphenyl

2-methoxy-1,1'-biphenyl

3-methoxybiphenyl

Refernces