N-diethoxyphosphinoyl-3-methoxybenzaldimine

Base Information

• Chemical Name: N-diethoxyphosphinoyl-3-methoxybenzaldimine
• CAS No.: 1095991-81-3
• Molecular Formula: C₁₂H₁₈NO₄P
• Molecular Weight: 271.253
• Mol file: 1095991-81-3.mol

Synonyms:N-diethoxyphosphinoyl-3-methoxybenzaldimine

Chemical Property of N-diethoxyphosphinoyl-3-methoxybenzaldimine

Chemical Property:

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Technology Process of N-diethoxyphosphinoyl-3-methoxybenzaldimine

There total 1 articles about N-diethoxyphosphinoyl-3-methoxybenzaldimine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 41.0%

Diethyl phosphoramidate (1068-21-9) + 3-methoxybenzaldehyde diethyl acetal (2403-47-6) → N-diethoxyphosphinoyl-3-methoxybenzaldimine (1095991-81-3)

Guidance literature:

at 160 ℃; for 0.5h; Reduced pressure; Inert atmosphere;

DOI:10.1021/ol802569q

Reference yield: 82.0%

α-methoxycarbonyl-α-phenyl-γ-methylidene-δ-valerolactone (958000-84-5) + N-diethoxyphosphinoyl-3-methoxybenzaldimine (1095991-81-3) → C25H32NO6P + C25H32NO6P

Guidance literature:

With 1,1'-bis(diphenylphosphino)ferrocene; PdCp(η3-C3H5); In toluene; at 20 ℃; for 24h; optical yield given as %de; diastereoselective reaction; Inert atmosphere;

DOI:10.1021/ol802569q

upstream raw materials:

Diethyl phosphoramidate

3-methoxybenzaldehyde diethyl acetal

Refernces