L-ascorbyl radical

Base Information

• Chemical Name: L-ascorbyl radical
• CAS No.: 63983-50-6
• Molecular Formula: C₆H₆O₆
• Molecular Weight: 174.11
• Mol file: 63983-50-6.mol

Synonyms:L-ascorbyl radical

Chemical Property of L-ascorbyl radical

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of L-ascorbyl radical

There total 27 articles about L-ascorbyl radical which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

ascorbate (299-36-5) → ascorbic acid radical anion (63983-50-6)

Guidance literature:

With Nitrosobenzene; In 1,4-dioxane; water; at 24.84 ℃; Further Variations:; Solvents; Kinetics;

DOI:10.1016/j.tetlet.2007.03.140

Reference yield:

ascorbate (299-36-5) + fluoromethyl peroxy radical (119437-63-7) → ascorbic acid radical anion (63983-50-6) + fluoromethyl peroxate (137848-37-4)

Guidance literature:

With R₃₂; oxygen; In water; isopropyl alcohol; Rate constant;

DOI:10.1021/j100347a045

Reference yield:

(1-hydroxy-1-methyl-ethyl)-peroxyl (25415-02-5) + ascorbate (299-36-5) → 2-hydroxy-2-propylhydroperoxide (19393-66-9) + ascorbic acid radical anion (63983-50-6)

Guidance literature:

With oxygen; dinitrogen monoxide; In water; isopropyl alcohol; Rate constant;

DOI:10.1021/j100347a045

upstream raw materials:

(1-hydroxy-1-methyl-ethyl)-peroxyl

ascorbate

Benzylperoxyradikal

Peroxidradikal v. Diphenylmethan

Downstream raw materials:

5-(1,2-Dihydroxy-ethyl)-3,4-dihydroxy-5H-furan-2-one

Refernces

• 1、 Warren, Jeffrey J.,Mayer, James M.. "Predicting organic hydrogen atom transfer rate constants using the Marcus cross relation". scheme or table. p. 5282 - 5287. Retrieved 2010/09/10.
• 2、 Neta, P.,Huie, R. E.,Mosseri, S.,Shastri, L. V.,Mittal, J. P.,et al.. "Rate Constants for Reduction of substituted Methylperoxyl Radicals by Ascorbate Ions and N,N,N',N'-tetramethyl-p-phenylenediamine". . p. 4099 - 4104. Retrieved 2007/10/02.