CID 53628098

Base Information

• Chemical Name: CID 53628098
• CAS No.: 811-49-4
• Molecular Formula: C2H5 Li
• Molecular Weight: 36.0027
• Hs Code.: 29319090
• Nikkaji Number: J542H
• Mol file: 811-49-4.mol

Synonyms:

Chemical Property of CID 53628098

Chemical Property:

• Melting Point: 95℃
• Flash Point: ?17 ºF
• PSA: 0.00000
• Density: 0.862 g/mL at 25 ºC
• LogP: 0.97390
• Storage Temp.: Refrigerator (+4°C) + Flammables area
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 36.05512859
• Heavy Atom Count: 3
• Complexity: 0

Purity/Quality:

98%,99%, ^*data from raw suppliers

Ethyllithium solution 0.5 M in benzene: cyclohexane ^*data from reagent suppliers

Safty Information:

• Pictogram(s): TF
• Hazard Codes: F,T,N
• Statements: 45-46-11-36/38-48/23/24/25-65-51/53
• Safety Statements: 53-36/37-45-62-61-26-16

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [Li].C[CH2]
• Uses: Ethyllithium is a general organolithium reagent used in the nucleophilic addition reaction to synthesize a variety of intermediates.

Technology Process of CID 53628098

There total 12 articles about CID 53628098 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

n-butyllithium (109-72-8,29786-93-4) + ethyl iodide (75-03-6) → 1-iodo-butane (542-69-8) + ethyllithium (811-49-4)

Guidance literature:

reversible Reaktion;

DOI:10.1021/ja01850a087

Reference yield:

→ dibutyl ether (142-96-1) + ethyllithium (811-49-4)

Guidance literature:

Reference yield:

ethyl bromide (74-96-4) → ethyllithium (811-49-4)

Guidance literature:

With lithium; Petroleum ether;

DOI:10.1039/jr9410000323 DOI:10.1002/hlca.19480310408

upstream raw materials:

ethyl bromide

diethylmercury

n-butyllithium

ethyl iodide

Downstream raw materials:

tetraethyltin

diphenylmercury(II)

ethyl isopropyl ketone

1.1.3-trimethyl-2-(2³-metho-penten-(2¹)-ylol-(2³))-cyclohexene-⁽²⁾

Refernces

• 1、 Shklyaruck, Denis G.,Fedarkevich, Artsiom N.,Kozyrkov, Yurii Yu.. "Transition-metal-free stereoselective synthesis of C(1)–C(6) fragment of epothilones and their structural analogues". . p. 8015 - 8021. Retrieved 2016/11/22.
• 2、 -. "Vitamin D analogues". Page column 20. . Retrieved 2010/02/05.