1-[4-(di-(p-tolyl)amino)phenyl]-3-(triphenyl)phosphoniumpropyl-1-ene bromide

Base Information

• Chemical Name: 1-[4-(di-(p-tolyl)amino)phenyl]-3-(triphenyl)phosphoniumpropyl-1-ene bromide
• CAS No.: 1355320-79-4
• Molecular Formula: Br*C₄₁H₃₇NP
• Molecular Weight: 654.629
• Mol file: 1355320-79-4.mol

Synonyms:1-[4-(di-(p-tolyl)amino)phenyl]-3-(triphenyl)phosphoniumpropyl-1-ene bromide

Chemical Property of 1-[4-(di-(p-tolyl)amino)phenyl]-3-(triphenyl)phosphoniumpropyl-1-ene bromide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-[4-(di-(p-tolyl)amino)phenyl]-3-(triphenyl)phosphoniumpropyl-1-ene bromide

There total 9 articles about 1-[4-(di-(p-tolyl)amino)phenyl]-3-(triphenyl)phosphoniumpropyl-1-ene bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

3-(4-(N,N-di-(p-tolyl)amino)phenyl)prop-2-en-1-ol + triphenylphosphine hydrobromide (6399-81-1) → 1-[4-(di-(p-tolyl)amino)phenyl]-3-(triphenyl)phosphoniumpropyl-1-ene bromide (1355320-79-4)

Guidance literature:

for 2h; Reflux;

DOI:10.1039/c5tc02559a

Reference yield:

4-[N,N-di(p-tolyl)amino]benzaldehyde (101089-53-6) → 1-[4-(di-(p-tolyl)amino)phenyl]-3-(triphenyl)phosphoniumpropyl-1-ene bromide (1355320-79-4)

Guidance literature:

Multi-step reaction with 4 steps

1: potassium tert-butylate / tetrahydrofuran / 4 h / 0 - 20 °C / Inert atmosphere

2: trichlorophosphate / 5 h / 85 °C / Inert atmosphere

3: sodium tetrahydroborate / dichloromethane; ethanol / 1 h / Reflux

4: 2 h / Reflux

With sodium tetrahydroborate; potassium tert-butylate; trichlorophosphate; In tetrahydrofuran; ethanol; dichloromethane; 1: |Wittig-Horner Reaction;

DOI:10.1039/c5tc02559a

Reference yield:

4-methyl-N-p-tolyl-N-(4-vinylphenyl)benzenamine (74065-48-8) → 1-[4-(di-(p-tolyl)amino)phenyl]-3-(triphenyl)phosphoniumpropyl-1-ene bromide (1355320-79-4)

Guidance literature:

Multi-step reaction with 3 steps

1: trichlorophosphate / 5 h / 85 °C / Inert atmosphere

2: sodium tetrahydroborate / dichloromethane; ethanol / 1 h / Reflux

3: 2 h / Reflux

With sodium tetrahydroborate; trichlorophosphate; In ethanol; dichloromethane;

DOI:10.1039/c5tc02559a

upstream raw materials:

4-[N,N-di(p-tolyl)amino]benzaldehyde

N,N-diphenyl-N-(4-vinylphenyl)amine

C₂₁H₁₇NO

triphenylphosphine hydrobromide

Refernces

• 1、 Gao, Wenzheng,Wang, Shirong,Xiao, Yin,Li, Xianggao. "Synthesis and properties of new luminescent hole transporting materials containing triphenylamine and carbazole units". . p. 215 - 221,7. Retrieved 2012/12/12.