[(η5-pentamethylcyclopentadienyl)RhI(CH2CH2CF(CF3)2)(PPh3)]

Base Information

• Chemical Name: [(η5-pentamethylcyclopentadienyl)RhI(CH2CH2CF(CF3)2)(PPh3)]
• CAS No.: 1349737-19-4
• Molecular Formula: C₃₃H₃₄F₇IPRh
• Molecular Weight: 824.406
• Mol file: 1349737-19-4.mol

Synonyms:[(η5-pentamethylcyclopentadienyl)RhI(CH2CH2CF(CF3)2)(PPh3)]

Chemical Property of [(η5-pentamethylcyclopentadienyl)RhI(CH2CH2CF(CF3)2)(PPh3)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(η5-pentamethylcyclopentadienyl)RhI(CH2CH2CF(CF3)2)(PPh3)]

There total 1 articles about [(η5-pentamethylcyclopentadienyl)RhI(CH2CH2CF(CF3)2)(PPh3)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

[(η5-pentamethylcyclopentadienyl)2Rh2I(μ-I)2(CH2CH2CF(CF3)2)] (1349736-92-0) + [(η5-pentamethylcyclopentadienyl)2Rh2(μ-I)2(CH2CH2CF(CF3)2)2]*benzene-d6 (1350458-19-3) + triphenylphosphine (603-35-0) → 1,1,1,2,2,3,3-heptafluoro-3-iodo-propane (754-34-7) + [(η5-pentamethylcyclopentadienyl)RhI(CH2CH2CF(CF3)2)(PPh3)] (1349737-19-4)

Guidance literature:

In tetrahydrofuran; byproducts: CH2CH2; (N2, Schlenk technique); stirring mixt. of rhodium compds. and phosphinederiv. in THF for 5 h; evapn. in vac., chromy. (silica gel, diethyl ether/hexane (1:1)), evapn., elem. anal.;

DOI:10.1021/om2009588

Reference yield: 87.0%

2,6-dimethylphenyl isonitrile (119072-54-7,2769-71-3) + [(η5-pentamethylcyclopentadienyl)RhI(CH2CH2CF(CF3)2)(PPh3)] (1349737-19-4) + silver trifluoromethanesulfonate (2923-28-6) → [(η5-pentamethylcyclopentadienyl)Rh(CH2CH2CF(CF3)2)(PPh3)(CNXy)]OTf (1349737-00-3)

Guidance literature:

In dichloromethane; byproducts: AgCl; (N2, Schlenk technique); addn. of silver compd. to THF soln. of rhodium compd., stirring for 2 h, evapn., stirring with CH2Cl2, filtration, addn. of isocyanide deriv., stirring for 5 h at room temp.; evapn., washing with diethyl ether, drying in vac., elem. anal.;

DOI:10.1021/om2009588

Reference yield: 69.0%

carbon monoxide (201230-82-2) + [(η5-pentamethylcyclopentadienyl)RhI(CH2CH2CF(CF3)2)(PPh3)] (1349737-19-4) + silver trifluoromethanesulfonate (2923-28-6) → [(η5-pentamethylcyclopentadienyl)Rh(COCH2CH2CF(CF3)2)(PPh3)(CO)]OTf (1349737-04-7)

Guidance literature:

In dichloromethane; byproducts: AgCl; (N2, Schlenk technique); addn. of silver compd. to THF soln. of rhodium compd., stirring for 2 h at room temp., evapn., stirring with CH2Cl2, filtration, bubbling CO through filtrate for 3 min, stirring for 48 h at room temp.; filtration, evapn., washing with n-pentane, recrystn. by slow diffusion of n-pentane into CH2Cl2, elem. anal.;

DOI:10.1021/om2009588

upstream raw materials:

[(η5-pentamethylcyclopentadienyl)2Rh2I(μ-I)2(CH2CH2CF(CF3)2)]

[(η5-pentamethylcyclopentadienyl)2Rh2(μ-I)2(CH2CH2CF(CF3)2)2]*benzene-d6

triphenylphosphine

Downstream raw materials:

[(η5-pentamethylcyclopentadienyl)Rh(CH2CH2CF(CF3)2)(PPh3)(CNXy)]OTf

[(η5-pentamethylcyclopentadienyl)Rh(COCH2CH2CF(CF3)2)(PPh3)(CO)]OTf

Refernces