Carbamodithioic acid, dimethyl-, 2-(hydroxyimino)propyl ester

Base Information

• Chemical Name: Carbamodithioic acid, dimethyl-, 2-(hydroxyimino)propyl ester
• CAS No.: 34683-69-7
• Molecular Formula: C6H12N2OS2
• Molecular Weight: 192.3023
• Mol file: 34683-69-7.mol

Synonyms:Dimethyldithiocarbamic acid acetonyl ester oxime;CARBAMIC ACID, DIMETHYLDITHIO-, ACETONYL ESTER, OXIME;Carbamodithioic acid, dimethyl-, 2-(hydroxyimino)propyl ester;Dimethyldithiocarbamic acid ester with mercapto-2-propanone oxime;34683-69-7;SCHEMBL11760952;LS-49519

Chemical Property of Carbamodithioic acid, dimethyl-, 2-(hydroxyimino)propyl ester

Chemical Property:

• Vapor Pressure: 0mmHg at 25°C
• Boiling Point: 298.048°C at 760 mmHg
• Flash Point: 134.055°C
• Density: 1.184g/cm³
• XLogP3: 1.3
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 3
• Exact Mass: 192.03910536
• Heavy Atom Count: 11
• Complexity: 168

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CC(=NO)CSC(=S)N(C)C
• Isomeric SMILES: C/C(=N\O)/CSC(=S)N(C)C

Technology Process of Carbamodithioic acid, dimethyl-, 2-(hydroxyimino)propyl ester

There total 2 articles about Carbamodithioic acid, dimethyl-, 2-(hydroxyimino)propyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 47.0%

chloroacetone oxime (671-59-0) + sodium dimethyldithiocarbamate (128-04-1) → dimethyl-dithiocarbamic acid-(2-hydroxyimino-propyl ester) (34683-69-7)

Guidance literature:

In ethanol; for 18h; Ambient temperature;

DOI:10.1055/s-1987-27940

Reference yield:

1-(dimethylaminothiocarbonylthio)propan-2-one (19204-12-7) → dimethyl-dithiocarbamic acid-(2-hydroxyimino-propyl ester) (34683-69-7)

Guidance literature:

With hydroxylamine;

Reference yield:

dimethyl-dithiocarbamic acid-(2-hydroxyimino-propyl ester) (34683-69-7) → dimethyl-dithiocarbamic acid-(2-benzoyloxyimino-propyl ester)

Guidance literature:

upstream raw materials:

1-(dimethylaminothiocarbonylthio)propan-2-one

chloroacetone oxime

sodium dimethyldithiocarbamate

Refernces