2,6-diisopropylphenyl isocyanide

Base Information

• Chemical Name: 2,6-diisopropylphenyl isocyanide
• CAS No.: 154079-07-9
• Molecular Formula: C₁₃H₁₇N
• Molecular Weight: 187.285
• Mol file: 154079-07-9.mol

Synonyms:2,6-diisopropylphenyl isocyanide

Chemical Property of 2,6-diisopropylphenyl isocyanide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of 2,6-diisopropylphenyl isocyanide

There total 3 articles about 2,6-diisopropylphenyl isocyanide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 13.0%

2,6-diisopropylbenzenamine (24544-04-5) → 1,3-diisopropylbenzene (99-62-7) + 1,3-diisopropyl-2-nitrobenzene (91563-76-7) + 2,6-diisopropylphenyl isocyanide (154079-07-9) + 1,3-Diisopropyl-2-nitrosooxy-benzene

Guidance literature:

With tert.-butylnitrite; In dimethyl sulfoxide; at 60 ℃; for 1.5h;

DOI:10.1016/0040-4020(96)00331-6

Reference yield: 13.0%

2,6-diisopropylbenzenamine (24544-04-5) + copper(I) cyanide (544-92-3) → 1,3-diisopropylbenzene (99-62-7) + 1,3-diisopropyl-2-nitrobenzene (91563-76-7) + 2,6-diisopropylphenyl isocyanide (154079-07-9) + 1,3-Diisopropyl-2-nitrosooxy-benzene

Guidance literature:

With tert.-butylnitrite; In dimethyl sulfoxide; at 60 ℃; for 1.5h;

DOI:10.1016/0040-4020(96)00331-6

Reference yield:

2,6-diisopropylbenzenamine (24544-04-5) + copper(I) cyanide (544-92-3) → 2,6-diisopropylphenyl isocyanide (154079-07-9)

Guidance literature:

With pyridine; Bromotrichloromethane; isopentyl nitrite; Yield given. Multistep reaction; 1.) DME, 75 deg C, 14 h, 2.) 240 deg C, 18 h;

upstream raw materials:

2,6-diisopropylbenzenamine

copper(I) cyanide

Downstream raw materials:

Pd(N=C=N-2,6-C₆H₃-i-Pr₂)(N,N'-dimethylbenzylamine)PMe₃(C=N-C₆H₃-2,6-i-Pr₂)

Pd(N₃)(N,N'-dimethylbenzylamine)PMe₃(C=N-C₆H₃-2,6-i-Pr₂)

1-(2,6-diisopropylphenyl)-1-iminoethane

Refernces

• 1、 Knorr, Rudolf,Ruhdorfer, Jakob,Boehrer, Petra,Bronberger, Hildegard,Raepple, Edith. "Sterically Congested Molecules, 11. The 2,6-Diisopropylphenyl Substituent at C=C and C=N Groups". . p. 433 - 438. Retrieved 2007/10/02.