Phenyldimethylethoxysilane

Base Information

• Chemical Name: Phenyldimethylethoxysilane
• CAS No.: 1825-58-7
• Molecular Formula: C10H16OSi
• Molecular Weight: 180.322
• Hs Code.: 2931900090
• European Community (EC) Number: 217-366-4
• NSC Number: 96880
• UNII: UC6LV98FAY
• DSSTox Substance ID: DTXSID0062000
• Nikkaji Number: J44.175I
• Wikidata: Q72470279
• Mol file: 1825-58-7.mol

Synonyms:Silane,ethoxydimethylphenyl- (6CI,7CI,8CI,9CI);Dimethylethoxyphenylsilane;Ethoxydimethylphenylsilane;NSC 96880;

Chemical Property of Phenyldimethylethoxysilane

Chemical Property:

• Appearance/Colour: Colorless or yellowish transparent liquid
• Vapor Pressure: 0.3mmHg at 25°C
• Melting Point: <0°C
• Refractive Index: n20/D 1.479
• Boiling Point: 208.997 °C at 760 mmHg
• Flash Point: 73.074 °C
• PSA: 9.23000
• Density: 0.912 g/cm³
• LogP: 2.13520
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 180.097041664
• Heavy Atom Count: 12
• Complexity: 128

Purity/Quality:

98% ^*data from raw suppliers

Ethoxydimethylphenylsilane ≥97.0% (GC) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCO[Si](C)(C)C1=CC=CC=C1
• Uses: Ethoxydimethylphenylsilane can be used:To functionalize SiO2 nanoparticles by the sol-gel method used in the bilayer coatings on a glass surface.To functionalize the nanosized zeolites applicable in the catalysis.As a substrate in the study of Si-O bond cleavage in the presence of serine hydrolases.

Technology Process of Phenyldimethylethoxysilane

There total 42 articles about Phenyldimethylethoxysilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

ethanol (64-17-5) + dimethylphenylvinylsilane (1125-26-4) → ethene (74-85-1) + dimethyl(ethoxy)phenylsilane (1825-58-7)

Guidance literature:

hydrogenchloride; chlorobis(cyclooctene)rhodium(I) dimer; In 1,4-dioxane; chloroform; at 20 ℃; for 18h; Kinetics;

Reference yield: 99.0%

ethanol (64-17-5) + Dimethylphenylsilane (766-77-8) → dimethyl(ethoxy)phenylsilane (1825-58-7)

Guidance literature:

With NTf₂^- modified porous organic polymer stabilized ultrasmall platinum nanoparticles; at 70 ℃; for 10h; Reagent/catalyst;

DOI:10.1007/s10562-021-03763-w

Reference yield: 98.1%

cyclohexanone (108-94-1,11119-77-0,9003-41-2,9075-99-4) + benzene-1,2-diol (120-80-9,19481-10-8,37349-32-9) → spiro[benzo[d][1,3]dioxole-2,1'-cyclohexane] (182-55-8)

Guidance literature:

With Cu(II) impregnated sulfated MCM-41; In toluene; benzene; for 1h; Reflux;

DOI:10.1080/15533174.2010.538018

upstream raw materials:

diethoxy dimethylsilane

chloromethyldimethylphenylsilane

sodium ethanolate

ethanol

Downstream raw materials:

ethanol

dimethylphenylsilanol

Dimethylphenylsilane

sodium phenyldimethylsilanolate

Refernces

• 1、 Chen, Chao,Cheng, Dan,Ding, Shunmin,Liang, Sanqi,Liu, Senqun,Ma, Xiaohua,Su, Tongtong,Wu, Shaohua,Zeng, Rong. "Charge Modified Porous Organic Polymer Stabilized Ultrasmall Platinum Nanoparticles for the Catalytic Dehydrogenative Coupling of Silanes with Alcohols". . . Retrieved 2021/08/12.
• 2、 Li, Li,Wu, Shi-Lu,Xu, Li-Wen,Xu, Zheng,Yan, Jun-Hao,Yang, Ke-Fang,Yang, Meng-Meng,Yin, Guan-Wu,Zhang, Peng-Fei. "Swollen-induced in-situ encapsulation of chiral silver catalysts in cross-linked polysiloxane elastomers: Homogeneous reaction and heterogeneous separation". . . Retrieved 2021/09/28.