Zr(C₅H₅)2(C₆H₅)2(C₆H₅)2SiC₄

Base Information

• Chemical Name: Zr(C₅H₅)2(C₆H₅)2(C₆H₅)2SiC₄
• CAS No.: 163237-36-3
• Molecular Formula: C₃₈H₃₀SiZr
• Molecular Weight: 605.966
• Mol file: 163237-36-3.mol

Synonyms:Zr(C₅H₅)2(C₆H₅)2(C₆H₅)2SiC₄

Chemical Property of Zr(C₅H₅)2(C₆H₅)2(C₆H₅)2SiC₄

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Zr(C₅H₅)2(C₆H₅)2(C₆H₅)2SiC₄

There total 2 articles about Zr(C₅H₅)2(C₆H₅)2(C₆H₅)2SiC₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

zirconocene dichloride (1291-32-3) + 1,1-diphenylbis(phenylethynyl)silane (18784-61-7) → Zr(C5H5)2(C6H5)2(C6H5)2SiC4 (163237-36-3)

Guidance literature:

With n-BuLi; In tetrahydrofuran; hexane; (N2); stirring (-78°C, 1 h), warming to 0°C, pptn., cooling to -20°C, warming to room temp. (3 h); filtration, crystn.(-40°C); elem. anal.;

DOI:10.1021/ja972381v

Reference yield:

zirconocene(ethylene) complex + 1,1-diphenylbis(phenylethynyl)silane (18784-61-7) → Zr(C5H5)2(C6H5)2(C6H5)2SiC4 (163237-36-3)

Guidance literature:

DOI:10.1021/ja00114a038

upstream raw materials:

1,1-diphenylbis(phenylethynyl)silane

zirconocene dichloride

Refernces

• 1、 Takahashi, Tamotsu,Xi, Zhenfeng,Obora, Yasushi,Suzuki, Noriyuki. "Intramolecular coupling of alkynyl groups of bis(alkynyl)silane mediated by zirconocene compounds: Formation of silacyclobutene derivatives". . p. 2665 - 2666. Retrieved 2007/10/02.