Styrene, 4-chloro-beta,beta-dimethyl-

Base Information

• Chemical Name: Styrene, 4-chloro-beta,beta-dimethyl-
• CAS No.: 19366-15-5
• Molecular Formula: C10H11 Cl
• Molecular Weight: 166.65
• Hs Code.: 2903999090
• European Community (EC) Number: 654-829-3
• DSSTox Substance ID: DTXSID60172974
• Nikkaji Number: J49.494A
• Mol file: 19366-15-5.mol

Synonyms:Styrene, 4-chloro-beta,beta-dimethyl-;4-Chloro-beta,beta-dimethylstyrene;19366-15-5;BRN 2040728;1-chloro-4-(2-methylprop-1-enyl)benzene;4-05-00-01381 (Beilstein Handbook Reference);1-chloro-4-(2-methylprop-1-en-1-yl)benzene;1-Isobutenyl-4-chlorobenzene;SCHEMBL9494242;2-methyl-1-p-chlorophenylpropene;DTXSID60172974;AKOS006283787;p-chloro-(2-methyl-1-propenyl)benzene;LS-147210;Benzene, 1-chloro-4-(2-methyl-1-propenyl)-

Chemical Property of Styrene, 4-chloro-beta,beta-dimethyl-

Chemical Property:

• Vapor Pressure: 0.103mmHg at 25°C
• Boiling Point: 229.7°Cat760mmHg
• Flash Point: 88.1°C
• PSA: 0.00000
• Density: 1.05g/cm³
• LogP: 3.76320
• XLogP3: 4.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 1
• Exact Mass: 166.0549280
• Heavy Atom Count: 11
• Complexity: 137

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=CC1=CC=C(C=C1)Cl)C

Technology Process of Styrene, 4-chloro-beta,beta-dimethyl-

There total 21 articles about Styrene, 4-chloro-beta,beta-dimethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

4-chlorobenzaldehyde (104-88-1) + acetone (67-64-1) → 4-chloro-β,β-dimethylstyrene (19366-15-5) + 4,4'-dichlorostylbene (5121-74-4)

Guidance literature:

With aluminium trichloride; zinc; In acetonitrile; for 19h; Heating;

DOI:10.1016/s0040-4039(00)01034-0

Reference yield: 72.0%

C14H24ClN2O2P → 4-chloro-β,β-dimethylstyrene (19366-15-5)

Guidance literature:

With silica gel; In toluene; for 5h; Heating;

Reference yield: 60.0%

1-(4'-chlorophenyl)-2-methyl-1-propanol (10400-18-7) → 4-chloro-β,β-dimethylstyrene (19366-15-5)

Guidance literature:

With sulfuric acid; acetic anhydride; for 4h; Heating;

DOI:10.1248/cpb.34.4653

upstream raw materials:

1-(4'-chlorophenyl)-2-methyl-1-propanol

2-(4-chlorophenyl)-3,3-dimethyloxetane

1-chloro-4-(β-chloro-isobutyl)-benzene

1-(4-chlorophenyl)-2-methyl-2-propanol

Downstream raw materials:

(+/-)-3t-(4-chloro-phenyl)-2,2-dimethyl-cyclopropane-r-carboxylic acid

2-p-chlorophenyl-3,3-dimethyl-1,1,-dichlorocyclopropane

4-chloro-1-(2-methylpropyl)benzene

Chlorphentermine

Refernces

• 1、 Chen, Kun-Quan,Shen, Jie,Wang, Zhi-Xiang,Chen, Xiang-Yu. "A donor-acceptor complex enables the synthesis of: E -olefins from alcohols, amines and carboxylic acids". . p. 6684 - 6690. Retrieved 2021/05/31.
• 2、 Albright, Haley,Schindler, Corinna S.,Vonesh, Hannah L.. "Superelectrophilic Fe(III)-Ion Pairs as Stronger Lewis Acid Catalysts for (E)-Selective Intermolecular Carbonyl-Olefin Metathesis". supporting information. p. 3155 - 3160. Retrieved 2020/04/21.