9,10-Dihydro-9,10-dioxoanthracenediazonium hydrogen sulphate

Base Information

• Chemical Name: 9,10-Dihydro-9,10-dioxoanthracenediazonium hydrogen sulphate
• CAS No.: 82-37-1
• Deprecated CAS: 51143-41-0
• Molecular Formula: C₁₄H₇N₂O₂*HO₄S
• Molecular Weight: 332.293
• European Community (EC) Number: 201-416-7
• UNII: Y054MV6273
• DSSTox Substance ID: DTXSID30890491
• Wikidata: Q27294092
• Mol file: 82-37-1.mol

Synonyms:1-Anthraquinonediazonium sulfate;82-37-1;9,10-Dihydro-9,10-dioxoanthracenediazonium hydrogen sulphate;EINECS 201-416-7;1-Anthracenediazonium, 9,10-dihydro-9,10-dioxo-, sulfate (1:1);UNII-Y054MV6273;Y054MV6273;C14H7N2O2.HO4S;SCHEMBL11286378;AZOIC DIAZO COMPONENT 36;DTXSID30890491;anthraquinonediazonium hydrogensulfate;C14-H7-N2-O2.H-O4-S;1-anthraquinonediazonium hydrogen sulfate;Q27294092;9,10-dioxo-9,10-dihydroanthracene-1-diazonium hydrogen sulfate

Chemical Property of 9,10-Dihydro-9,10-dioxoanthracenediazonium hydrogen sulphate

Chemical Property:

• PSA: 148.10000
• LogP: 3.03198
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 7
• Rotatable Bond Count: 0
• Exact Mass: 332.01030715
• Heavy Atom Count: 23
• Complexity: 512

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C2C(=C1)C(=O)C3=C(C2=O)C(=CC=C3)[N+]#N.OS(=O)(=O)[O-]

Technology Process of 9,10-Dihydro-9,10-dioxoanthracenediazonium hydrogen sulphate

There total 2 articles about 9,10-Dihydro-9,10-dioxoanthracenediazonium hydrogen sulphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-amino-9,10-anthracenedione (82-45-1) → 9,10-dioxo-9,10-dihydroanthracene-1-diazonium hydrogen sulfate (82-37-1)

Guidance literature:

With sulfuric acid; sodium nitrite; at 0 - 5 ℃; for 1h;

DOI:10.1021/cm502866e

Reference yield:

→ 9,10-dioxo-9,10-dihydroanthracene-1-diazonium hydrogen sulfate (82-37-1)

Guidance literature:

zur Bildung;

Reference yield:

9,10-dioxo-9,10-dihydroanthracene-1-diazonium hydrogen sulfate (82-37-1) → 1-fluoro-9,10-anthraquinone (569-06-2)

Guidance literature:

Multi-step reaction with 2 steps

1: water / 2 h / 0 °C

2: 24 h / 300 °C

In water;

DOI:10.1021/cm502866e

upstream raw materials:

1-amino-9,10-anthracenedione

Downstream raw materials:

5-Cyclohexylamino-6-oxo-6H-anthra[9,1-bc]furan-2-carboxylic acid methyl ester

1-fluoro-9,10-anthraquinone

1-fluoroanthracene

Refernces

• 1、 Sabadakh,Taras,Luchkevich,Novikov. "Synthesis of triazene derivatives of 9,10-anthraquinone". . p. 277 - 278. Retrieved 2015/04/14.