Vinyltris(tert-butylperoxy)silane

Base Information

• Chemical Name: Vinyltris(tert-butylperoxy)silane
• CAS No.: 15188-09-7
• Molecular Formula: C14H30O6Si
• Molecular Weight: 322.474
• Hs Code.: 2931900090
• European Community (EC) Number: 239-238-7
• DSSTox Substance ID: DTXSID60934357
• Nikkaji Number: J539.511I
• Wikidata: Q72515399
• Mol file: 15188-09-7.mol

Synonyms:Vinyltris(tert-butylperoxy)silane;15188-09-7;Tris(tert-butyldioxy)vinylsilane;tris(tert-butylperoxy)-ethenylsilane;Vinyltris(t-butylperoxy)silane;Vinyltris(tert-butyldioxy)silane;Silane 32-61;Silane, tris((1,1-dimethylethyl)dioxy)ethenyl-;Tris(tert-butylperoxy)vinylsilane;EINECS 239-238-7;Tris((1,1-dimethylethyl)dioxy)ethenylsilane;Silane, tris(tert-butyldioxy)vinyl-;X 12-530;Silane, tris[(1,1-dimethylethyl)dioxy]ethenyl-;tris(tert-butylperoxy)(ethenyl)silane;C14H30O6Si;SCHEMBL597423;Tri-t-butylperoxymonovinylsilane;C14-H30-O6-Si;DTXSID60934357;vinyl-tris-(t-butylperoxy) silane;LS-145265;Peroxide, (vinylsilylidyne)tris(tert-butyl-;Peroxide, (vinylsilylidyne)tris(tert-butyl- (6CI,7CI);Peroxide, 1,1',1''-(ethenylsilylidyne)tris(2-(1,1-dimethylethyl)

Chemical Property of Vinyltris(tert-butylperoxy)silane

Chemical Property:

• Appearance/Colour: Colorless transparent liquid
• Vapor Pressure: 0.0101mmHg at 25°C
• Refractive Index: 1.434
• Boiling Point: 272.6 °C at 760 mmHg
• Flash Point: 103.6 °C
• PSA: 55.38000
• Density: 0.98 g/cm³
• LogP: 3.89060
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 10
• Exact Mass: 322.18116521
• Heavy Atom Count: 21
• Complexity: 278

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Metals -> Metalloid Compounds (Silicon)
• Canonical SMILES: CC(C)(C)OO[Si](C=C)(OOC(C)(C)C)OOC(C)(C)C
• Uses: 1-Vinyltri-(t-butylperoxy)silane is used to promote adhesion in polymer-to-metal bonding applications .

Technology Process of Vinyltris(tert-butylperoxy)silane

There total 1 articles about Vinyltris(tert-butylperoxy)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tert.-butylhydroperoxide (75-91-2) + trichlorovinylsilane (75-94-5) → vinyltri(tert-butylperoxysilane) (15188-09-7)

Guidance literature:

Multistep reaction; (i) DABCO, (ii) /BRN= 1743440/;

DOI:10.1021/jo00953a030

Reference yield:

vinyltri(tert-butylperoxysilane) (15188-09-7) → 2-methyl-1,2-epoxypropane (558-30-5) + methane (34557-54-5,27936-85-2) + acetone (67-64-1) + tert-butyl alcohol (75-65-0)

Guidance literature:

In hexane; at 25 ℃; Product distribution; Kinetics; Heating;

upstream raw materials:

tert.-butylhydroperoxide

trichlorovinylsilane

Downstream raw materials:

2-methyl-1,2-epoxypropane

methane

acetone

tert-butyl alcohol