lithium N-(3,5-dimethylphenyl)-tert-butylamide etherate

Base Information

• Chemical Name: lithium N-(3,5-dimethylphenyl)-tert-butylamide etherate
• CAS No.: 260265-93-8
• Molecular Formula: C₄H₁₀O*C₁₂H₁₈N*Li
• Molecular Weight: 257.345
• Mol file: 260265-93-8.mol

Synonyms:lithium N-(3,5-dimethylphenyl)-tert-butylamide etherate

Chemical Property of lithium N-(3,5-dimethylphenyl)-tert-butylamide etherate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of lithium N-(3,5-dimethylphenyl)-tert-butylamide etherate

There total 1 articles about lithium N-(3,5-dimethylphenyl)-tert-butylamide etherate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 57.0%

diethyl ether (60-29-7,927820-24-4) + N-(3,5-dimethylphenyl)-tert-butylamine (110993-40-3) → lithium N-(3,5-dimethylphenyl)-tert-butylamide etherate (260265-93-8)

Guidance literature:

N-(3,5-dimethylphenyl)-tert-butylamine; With n-butyllithium; In hexane; at -78 - 20 ℃; for 12.1667h; Inert atmosphere;

diethyl ether; In hexane; at -30 ℃; for 12h; Inert atmosphere;

DOI:10.15227/orgsyn.084.0163

Reference yield: 64.0%

UI3(tetrahydrofuran)4 (115450-92-5) + lithium N-(3,5-dimethylphenyl)-tert-butylamide etherate (260265-93-8) → IU(N(C(CH3)3)(C6H3(CH3)2))3 (383910-23-4)

Guidance literature:

In toluene; byproducts: LiI, reduced U(0); at -90 to 0°C;

DOI:10.1021/ja980095t

Reference yield: 34.0%

{(neopentylidene)(2,6-diisopropylphenylimido)(CF3SO2O)2(1,2-dimetoxyethane)molybdenum} + lithium N-(3,5-dimethylphenyl)-tert-butylamide etherate (260265-93-8) → Mo(N-2,6-i-Pr2C6H3)(CH-t-Bu)[N(t-Bu)(3,5-C6H3Me2)]2

Guidance literature:

In diethyl ether; under N2 atm. to suspn. Mo complex in ether at -30°C LiN(t-Bu)(3,5-C6H3Me2)(ether) in ether was added and stirred at room temp. for 1.5 h; volatiles were removed in vacuo, residue was extd. with pentane and stored at -30°C overnight; elem. anal.;

DOI:10.1021/om060430j

upstream raw materials:

diethyl ether

N-(3,5-dimethylphenyl)-tert-butylamine

Downstream raw materials:

IU(N(C(CH₃)3)(C₆H₃(CH₃)2))3

[(Me₃CC)W(OCMe(CF₃)2)2(N(3,5-C₆H₃Me₂)-t-Bu)]

Refernces