2,2'-Hexane-1,6-diylbisoxirane

Base Information

• Chemical Name: 2,2'-Hexane-1,6-diylbisoxirane
• CAS No.: 24854-67-9
• Molecular Formula: C10H18 O2
• Molecular Weight: 170.252
• European Community (EC) Number: 246-498-5
• NSC Number: 36649
• DSSTox Substance ID: DTXSID50947759
• Nikkaji Number: J286.404E
• Mol file: 24854-67-9.mol

Synonyms:1,2,9,10-Diepoxydecane;24854-67-9;2,2'-Hexane-1,6-diylbisoxirane;2-[6-(oxiran-2-yl)hexyl]oxirane;1,4-Bis(2,3-epoxypropyl)butane;EINECS 246-498-5;NSC 36649;BRN 0106876;DECANE, 1,2:9,10-DIEPOXY-;Oxirane, 2,2'-(1,6-hexanediyl)bis-;1,6-Di(oxiran-2-yl)hexane;4-19-00-00142 (Beilstein Handbook Reference);NSC36649;1,6-Dioxiranylhexane;1,4-diglycidyl butane;1,3-epoxypropyl)butane;Decane,2:9,10-diepoxy-;SCHEMBL1535670;DTXSID50947759;Oxirane,2'-(1,6-hexanediyl)bis-;GEO-03954;MFCD00069424;NSC-36649;AKOS006229867;2,2'-(Hexane-1,6-diyl)bis(oxirane);LS-59312;FT-0694166;J-640014;J-800016

Chemical Property of 2,2'-Hexane-1,6-diylbisoxirane

Chemical Property:

• Refractive Index: 1.4494 (estimate)
• Boiling Point: 239.9°C (rough estimate)
• Flash Point: 94.1oC
• PSA: 25.06000
• Density: 0.9409 (rough estimate)
• LogP: 2.12460
• XLogP3: 2.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 7
• Exact Mass: 170.130679813
• Heavy Atom Count: 12
• Complexity: 120

Purity/Quality:

99% ^*data from raw suppliers

1,2,9,10-DIEPOXYDECANE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1C(O1)CCCCCCC2CO2

Technology Process of 2,2'-Hexane-1,6-diylbisoxirane

There total 5 articles about 2,2'-Hexane-1,6-diylbisoxirane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

1,10-decadiene (1647-16-1) → rac/meso-1,2,9,10-diepoxydecane (24854-67-9)

Guidance literature:

With peracetic acid; manganese(II) perchlorate; ammonium bicarbonate; In water; acetic acid; acetonitrile; at 20 ℃; for 0.666667h;

DOI:10.1002/chem.200800759

Reference yield: 78.0%

2-(oct-7-en-1-yl)oxirane (85721-25-1) → rac/meso-1,2,9,10-diepoxydecane (24854-67-9)

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; In chloroform; water; for 48h;

DOI:10.1039/b920143b

Reference yield:

1,10-decadiene (1647-16-1) → rac/meso-1,2,9,10-diepoxydecane (24854-67-9) + 2-(oct-7-en-1-yl)oxirane (85721-25-1)

Guidance literature:

With tert.-butylhydroperoxide; In decane; at 89.84 ℃; for 7h; Inert atmosphere;

DOI:10.1039/c5cy01639h

upstream raw materials:

1,10-decadiene

1,9-decadiyne

2-(oct-7-en-1-yl)oxirane

Downstream raw materials:

benzyl ((S)-2-hydroxy-8-((R)-oxiran-2-yl)octyl)carbamate

benzyl ((S)-2-hydroxy-8-((S)-oxiran-2-yl)octyl)carbamate

(S)-8-((R)-oxiran-2-yl)octane-1,2-diol

2-(oct-7-en-1-yl)oxirane

Refernces

• 1、 Lu, Yu-Jing,Wong, Wing-Leung,Chow, Cheuk-Fai. "A surfactant-like ionic liquid with permanganate dissolved as a highly selective epoxidation system". . p. 25 - 28. Retrieved 2015/06/08.
• 2、 Griffiths, Peter C.,Fallis, Ian A.,James, Craig,Morgan, Ian R.,Brett, Gemma,Heenan, Richard K.,Schweins, Ralf,Grillo, Isabelle,Paul, Alison. "Structure-property relationships in metallosurfactants". experimental part. p. 1981 - 1989. Retrieved 2011/10/31.