2,4-dinitrophenyl trifluoromethanesulfonate

Base Information

• Chemical Name: 2,4-dinitrophenyl trifluoromethanesulfonate
• CAS No.: 32578-27-1
• Molecular Formula: C₇H₃F₃N₂O₇S
• Molecular Weight: 316.171
• Mol file: 32578-27-1.mol

Synonyms:2,4-dinitrophenyl trifluoromethanesulfonate

Chemical Property of 2,4-dinitrophenyl trifluoromethanesulfonate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2,4-dinitrophenyl trifluoromethanesulfonate

There total 4 articles about 2,4-dinitrophenyl trifluoromethanesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

2,4-Dinitrophenol (51-28-5) + trifluoromethylsulfonic anhydride (358-23-6) → 2,4-dinitrophenyl trifluoromethanesulfonate (32578-27-1)

Guidance literature:

With triethylamine; In dichloromethane; at -10 ℃; for 0.333333h;

DOI:10.1021/jo990559l

Reference yield: 80.0%

thallium(I) 2,4-dinitrophenoxide (32707-04-3) + trifluoromethylsulfonic anhydride (358-23-6) → 2,4-dinitrophenyl trifluoromethanesulfonate (32578-27-1) + thallium(I) triflate (73491-36-8)

Guidance literature:

Reference yield:

Phenyl triflate (17763-67-6) → 2,4-dinitrophenyl trifluoromethanesulfonate (32578-27-1)

Guidance literature:

With sulfuric acid; nitric acid;

DOI:10.1021/jo00867a007

upstream raw materials:

Phenyl triflate

2,4-Dinitrophenol

trifluoromethylsulfonic anhydride

thallium(I) 2,4-dinitrophenoxide

Downstream raw materials:

(4-tert-butyl-phenyl)-(2,4-dinitro-phenyl)-ether

N-phenyl-2,4-dinitroaniline

2,4-dinitrobromobenzene

Refernces

• 1、 Zhu, Jieping,Bigot, Antony,Elise, Marie,Dau, Tran Huu. "4-Nitrophenyltriflate as a New Triflating Agent". . p. 1181 - 1182. Retrieved 2007/10/03.