10-Oxoundecanoic acid

Base Information

• Chemical Name: 10-Oxoundecanoic acid
• CAS No.: 676-00-6
• Molecular Formula: C11H20O3
• Molecular Weight: 200.278
• Hs Code.: 2918300090
• Mol file: 676-00-6.mol

Synonyms:10-Ketoundecanoic acid;10-oxo-undecanoic acid;Undecanoic acid,10-oxo;9-acetyl pelargonic acid;10-Oxo-undecansaeure;

Chemical Property of 10-Oxoundecanoic acid

Chemical Property:

• Vapor Pressure: 7.5E-06mmHg at 25°C
• Boiling Point: 350.5°C at 760 mmHg
• Flash Point: 180°C
• PSA: 54.37000
• Density: 0.992g/cm³
• LogP: 2.78080

Purity/Quality:

98%,99%, ^*data from raw suppliers

10-OXOUNDECANOIC ACID Aldrich ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 10-Oxoundecanoic acid

There total 22 articles about 10-Oxoundecanoic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

10-undecenoic acid (112-38-9) → 10-oxo-undecanoic acid (676-00-6)

Guidance literature:

With water; oxygen; copper(l) chloride; In tetrahydrofuran; at 20 ℃; for 36h; under 759.826 Torr;

DOI:10.1002/cctc.201500241

Reference yield: 89.0%

10-hydroxyundecanoic acid (6336-28-3,35005-52-8,35005-53-9) → 10-oxo-undecanoic acid (676-00-6)

Guidance literature:

With Dess-Martin periodane; In dichloromethane; at 0 - 20 ℃; for 10h;

DOI:10.1021/jo5023553

Reference yield: 72.0%

undec-10-ynoic acid (2777-65-3) → 10-oxo-undecanoic acid (676-00-6) + 10-fluoroundec-10-enoic acid (175400-10-9)

Guidance literature:

With AuOH(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene); hydrogen fluoride; water; In toluene; at 50 ℃; for 18h; chemoselective reaction; Sealed tube;

DOI:10.1002/chem.202103886

upstream raw materials:

undecane-1,10-diol

9-undecynoic acid

10-hydroxyundecanoic acid

ethyl 10-oxo-decanecarboxylate

Downstream raw materials:

hexadecane-2,15-dione

2,11-dodecadione

Refernces

• 1、 Bédard, Sandrine,Cavallo, Luigi,Falivene, Laura,Gauthier, Rapha?l,Nolan, Steven P.,Paquin, Jean-Fran?ois,Saab, Marina,Tzouras, Nikolaos V.,Van Hecke, Kristof,Zhang, Ziyun. "Gold N-Heterocyclic Carbene Catalysts for the Hydrofluorination of Alkynes Using Hydrofluoric Acid: Reaction Scope, Mechanistic Studies and the Tracking of Elusive Intermediates". supporting information. . Retrieved 2021/12/09.
• 2、 Dong, Guangbin,Xu, Yan,Zhou, Xukai. "Olefination via Cu-Mediated Dehydroacylation of Unstrained Ketones". supporting information. p. 20042 - 20048. Retrieved 2021/12/03.