Disiloxane, 1,3-bis(2-bicyclo4.2.0octa-1,3,5-trien-3-ylethenyl)-1,1,3,3-tetramethyl-, homopolymer

Base Information

• Chemical Name: Disiloxane, 1,3-bis(2-bicyclo4.2.0octa-1,3,5-trien-3-ylethenyl)-1,1,3,3-tetramethyl-, homopolymer
• CAS No.: 124221-30-3
• Molecular Formula: C6H8O2
• Molecular Weight: 390.67
• Mol file: 124221-30-3.mol

Synonyms:Disiloxane, 1,3-bis(2-bicyclo4.2.0octa-1,3,5-trien-3-ylethenyl)-1,1,3,3-tetramethyl-, homopolymer;1,3-BIS(2-BICYCLO(4.2.0)OCTA-1,3,5-TRIEN-3-YLETHENYL)-1,1,3,3- TETRAMETHYLDISILOXANE, HOMOPOLYMER

Chemical Property of Disiloxane, 1,3-bis(2-bicyclo4.2.0octa-1,3,5-trien-3-ylethenyl)-1,1,3,3-tetramethyl-, homopolymer

Chemical Property:

• PSA: 37.30000
• LogP: 1.18130

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Disiloxane, 1,3-bis(2-bicyclo4.2.0octa-1,3,5-trien-3-ylethenyl)-1,1,3,3-tetramethyl-, homopolymer

There total 2 articles about Disiloxane, 1,3-bis(2-bicyclo4.2.0octa-1,3,5-trien-3-ylethenyl)-1,1,3,3-tetramethyl-, homopolymer which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 43.0%

1,1,3,3-Tetramethyldisiloxane (3277-26-7) + C10H8 (144597-22-8) → 1,3-bis(2-bicyclo[4.2.0]octa-1,3,5-trien-3-yl-ethenyl)-1,1,3,3-tetramethyldisiloxane (168086-20-2,124221-30-3) + 1-(1-(bicyclo[4.2.0]octa-1(6),2,4-trien-3-yl)vinyl)-3-(1-(bicyclo[4.2.0]octa-1,3,5-trien-3-yl)vinyl)-1,1,3,3-tetramethyldisiloxane + (E)-1-(1-(bicyclo[4.2.0]octa-1(6),2,4-trien-3-yl)vinyl)-3-(2-(bicyclo[4.2.0]octa-1(6),2,4-trien-3-yl)vinyl)-1,1,3,3-tetramethyldisiloxane

Guidance literature:

1,1,3,3-Tetramethyldisiloxane; C₁₀H₈; In toluene; at 110 ℃; for 0.0833333h;

With platinum 1,3-divinyl-1,1,3,3-tetramethyldisiloxane; In toluene; chemoselective reaction;

DOI:10.1002/chem.201605520

Reference yield:

C13H15F3O3SSi → 1,3-bis(2-bicyclo[4.2.0]octa-1,3,5-trien-3-yl-ethenyl)-1,1,3,3-tetramethyldisiloxane (168086-20-2,124221-30-3)

Guidance literature:

With water; In toluene; at 20 ℃; for 0.5h; Inert atmosphere;

DOI:10.1021/ja407748z

upstream raw materials:

1,1,3,3-Tetramethyldisiloxane

C₁₀H₈

Refernces

• 1、 Martin, Sara E. S.,Watson, Donald A.. "Preparation of vinyl silyl ethers and disiloxanes via the silyl-heck reaction of silyl ditriflates". supporting information. p. 13330 - 13333. Retrieved 2013/09/24.