Furil

Base Information

• Chemical Name: Furil
• CAS No.: 492-94-4
• Deprecated CAS: 594872-19-2
• Molecular Formula: C10H6 O4
• Molecular Weight: 190.155
• Hs Code.: 29321900
• European Community (EC) Number: 207-766-7
• NSC Number: 5561
• UNII: 3AFE4C3P1F
• DSSTox Substance ID: DTXSID3049413
• Nikkaji Number: J6.063A
• Wikipedia: Alpha-Furil
• Wikidata: Q4734902
• ChEMBL ID: CHEMBL371181
• Mol file: 492-94-4.mol

Synonyms:alpha-furil;furil

Chemical Property of Furil

Chemical Property:

• Appearance/Colour: White crystal or powder. Odorless.
• Vapor Pressure: 0.000971mmHg at 25°C
• Melting Point: 163-165ºC
• Refractive Index: 1.54
• Boiling Point: 302.7 ºC at 760 mmHg
• Flash Point: 138.4ºC
• PSA: 60.42000
• Density: 1.302 g/cm3
• LogP: 1.93820
• Storage Temp.: Sealed in dry,Room Temperature
• Solubility.: Chloroform (Slightly), Methanol (Slightly)
• XLogP3: 1.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 3
• Exact Mass: 190.02660867
• Heavy Atom Count: 14
• Complexity: 223

Purity/Quality:

98% ^*data from raw suppliers

Furil >98.0%(GC) ^*data from reagent suppliers

Safty Information:

• Safety Statements: 24/25

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1=COC(=C1)C(=O)C(=O)C2=CC=CO2
• Uses: Furil was used in preparation of dioxomolybdenum(VI) complexes in situ.

Technology Process of Furil

There total 29 articles about Furil which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

furoin (552-86-3) → furil (492-94-4)

Guidance literature:

With tris paraperiodate; In benzene; for 1h; Heating;

Reference yield: 97.0%

1,2-di-furan-2-yl-ethane-1,2-diol (4464-77-1,69314-24-5,69314-25-6,116204-42-3) → furil (492-94-4)

Guidance literature:

With ruthenium trichloride; bromamine T; In water; acetonitrile; at 80 ℃; for 0.0833333h; pH=8.4;

DOI:10.1081/SCC-200048974

Reference yield: 94.0%

furoin (552-86-3) → furil (492-94-4)

Guidance literature:

With triphenylantimony dibromide; 1,8-diazabicyclo[5.4.0]undec-7-ene; In dichloromethane; for 20h; Ambient temperature;

DOI:10.1246/cl.1985.1577

upstream raw materials:

ξ-1,2-di-[2]furyl-ethene-1,2-diol

furoin

furfural

1-octadecanol

Downstream raw materials:

furoin

2-furoic acid methyl ester

2,3-di(furan-2-yl)-6-phenylquinoxaline

2-(4-cyanophenylimino)-4,5-di(2-furyl)-1,3-dioxole

Refernces

• 1、 Xu, Zhen,Wang, Min,Fan, Weiyu,Zhao, Jinsheng,Wang, Huaisheng. "The synthesis of new donor-acceptor polymers containing the 2,3-di(2-furyl) quinoxaline moiety: Fast-switching, low-band-gap, p- and n-dopable, neutral green-colored materials". . p. 271 - 280. Retrieved 2015.
• 2、 He, Chunlin,Pang, Siping,Zhang, Qi,Zhang, Xun,Zhao, Cheng. "Oxidation of: O -dioxime by (diacetoxyiodo)benzene: Green and mild access to furoxans". supporting information. p. 1489 - 1493. Retrieved 2022/01/31.
• 3、 Dinjar, Kristijan,Djerdj, Igor,Koj?inovi?, Jelena,Kukovecz, ákos,Markovi?, Berislav,Mileti?, Aleksandar,Nagy, Sándor Balázs,Sapi, Andras,Stenzel, David,Széchenyi, Aleksandar,Szenti, Imre,Tang, Yushu,Tatar, Dalibor,Varga, Gábor,Ziegenheim, Szilveszter. "Sol-gel synthesis of ceria-zirconia-based high-entropy oxides as high-promotion catalysts for the synthesis of 1,2-diketones from aldehyde". . . Retrieved 2021/10/20.