2,3,3-Trifluoroacryloyl fluoride

Base Information

• Chemical Name: 2,3,3-Trifluoroacryloyl fluoride
• CAS No.: 667-49-2
• Molecular Formula: C3F4 O
• Molecular Weight: 128.026
• European Community (EC) Number: 211-568-6
• UNII: ZF3W7R89YQ
• DSSTox Substance ID: DTXSID00216846
• Nikkaji Number: J26.720A
• Mol file: 667-49-2.mol

Synonyms:2,3,3-Trifluoroacryloyl fluoride;667-49-2;EINECS 211-568-6;perfluoroacrylyl fluoride;trifluoroacrylyl fluoride;perfluoroacryloyl fluoride;trifluoroacryloyl fluoride;C3F4O;ZF3W7R89YQ;SCHEMBL927336;C3-F4-O;DTXSID00216846;SJGGAMMXIZFWSF-UHFFFAOYSA-N;2,3,3-Trifluoro-2-propenoyl fluoride;2-Propenoyl fluoride, 2,3,3-trifluoro-

Chemical Property of 2,3,3-Trifluoroacryloyl fluoride

Chemical Property:

• Vapor Pressure: 1330mmHg at 25°C
• Boiling Point: 9.8°C at 760 mmHg
• PSA: 17.07000
• Density: 1.419g/cm³
• LogP: 1.56010
• XLogP3: 1.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 1
• Exact Mass: 127.98852727
• Heavy Atom Count: 8
• Complexity: 134

Purity/Quality:

98%Min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(=C(F)F)(C(=O)F)F

Technology Process of 2,3,3-Trifluoroacryloyl fluoride

There total 14 articles about 2,3,3-Trifluoroacryloyl fluoride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

1,2,3,3,3-pentafluoro-1-(perfluoromethoxy)prop-1-ene (137741-09-4) → 2,3,3-trifluoroacryloyl fluoride (667-49-2)

Guidance literature:

With fluorosulfonylchloride; antimony pentafluoride;

DOI:10.1007/BF01172281

Reference yield: 47.0%

Ethyl pentafluoro-1-propenyl ether (666-92-2) → Methyl fluoride (593-53-3) + 2,3,3-trifluoroacryloyl fluoride (667-49-2)

Guidance literature:

antimony pentafluoride; In neat (no solvent);

DOI:10.1021/jo00195a025

Reference yield: 37.0%

C7O3F12 (871504-55-1) → perfluoro (5-methylene-2,2-dimethyl-1,3-dioxolane) (871504-56-2) + 2,3,3-trifluoroacryloyl fluoride (667-49-2) + 2,2,4-tris(trifluoromethyl)-5-fluoro-1,3-dioxole (130760-30-4) + Hexafluoroacetone (684-16-2)

Guidance literature:

DOI:10.1016/j.jfluchem.2007.08.009

upstream raw materials:

perfluoroallyl iodide

hexafluoro-1,3-butadiene

Ethyl pentafluoro-1-propenyl ether

2,3-dibromotrifluoropropionyl fluoride

Downstream raw materials:

2-Phenyl-1,4,4-trifluoro-3-chloro-2-cyclobutene-1-carboxylic Acid

2-<1-(Acetyloxy)cyclohexyl>-1,4,4-trifluoro-2-cyclobutene-1-carboxylic Acid

3,4-Difluoro-6-(p-isopropylphenyl)-2H-pyran-2-one

1-Phenyl-3,3,4-trifluoro-1-cyclobutene-4-carboxylic Acid

Refernces

• 1、 Knunyants,I.L. et al.. "-". . p. 595 - 601. Retrieved 1973.
• 2、 Murotani, Eisuke,Saito, Susumu,Sawaguchi, Masanori,Yamamoto, Hiromasa,Nakajima, Youji,Miyajima, Tatsuya,Okazoe, Takashi. "Synthesis and polymerization of a novel perfluorinated monomer". . p. 1131 - 1136. Retrieved 2008/02/10.