benzyl(hexadecyl)sulfane

Base Information

• Chemical Name: benzyl(hexadecyl)sulfane
• CAS No.: 100330-20-9
• Molecular Formula: C₂₃H₄₀S
• Molecular Weight: 348.637
• Mol file: 100330-20-9.mol

Synonyms:benzyl(hexadecyl)sulfane

Chemical Property of benzyl(hexadecyl)sulfane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of benzyl(hexadecyl)sulfane

There total 5 articles about benzyl(hexadecyl)sulfane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

16-mercaptohexadecanoate (2917-26-2) + benzyl bromide (100-39-0) → benzyl(hexadecyl)sulfane (100330-20-9)

Guidance literature:

With n-butyllithium; In tetrahydrofuran; hexane; for 0.333333h; Ambient temperature;

DOI:10.1016/S0040-4039(97)01352-X

Reference yield: 96.0%

phenylmethanethiol (100-53-8) + hexadecanyl bromide (112-82-3) → benzyl(hexadecyl)sulfane (100330-20-9)

Guidance literature:

With potassium carbonate; In N,N-dimethyl-formamide; for 2h; Ambient temperature;

DOI:10.1080/00397919208020489

Reference yield: 88.0%

n-cetyl thiocyanate (66143-73-5) + benzyl bromide (100-39-0) → benzyl(hexadecyl)sulfane (100330-20-9)

Guidance literature:

With samarium; In methanol; at 20 ℃; for 0.5h;

upstream raw materials:

16-mercaptohexadecanoate

benzyl chloride

1-Chlorohexadecan

phenylmethanethiol

Downstream raw materials:

1-Chlorohexadecan

Benzyl phenyl sulfide

3,3,6-Trimethyl-4-phenylmercapto-heptadien-(1,5)

benzyl chloride

Refernces

• 1、 Zhan, Zhuang-Ping,Lang, Kai. "A novel one pot synthesis of benzyl sulfides: Samarium-induced, benzyl bromide mediated reduction of alkyl thiocyanates and diaryl disulfides in methanol". . p. 443 - 444. Retrieved 2007/10/03.