9r.10c-bis-(4-fluoro-phenyl)-9.10-dihydro-phenanthrenediol-(9.10t)

Base Information

• Chemical Name: 9r.10c-bis-(4-fluoro-phenyl)-9.10-dihydro-phenanthrenediol-(9.10t)
• CAS No.: 424-83-9
• Molecular Formula: C₂₆H₁₈F₂O₂
• Molecular Weight: 400.425
• Mol file: 424-83-9.mol

Synonyms:9r.10c-bis-(4-fluoro-phenyl)-9.10-dihydro-phenanthrenediol-(9.10t)

Chemical Property of 9r.10c-bis-(4-fluoro-phenyl)-9.10-dihydro-phenanthrenediol-(9.10t)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 9r.10c-bis-(4-fluoro-phenyl)-9.10-dihydro-phenanthrenediol-(9.10t)

There total 2 articles about 9r.10c-bis-(4-fluoro-phenyl)-9.10-dihydro-phenanthrenediol-(9.10t) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2,2'-bis-(4-fluoro-benzoyl)-biphenyl (438-61-9) → 9r.10c-bis-(4-fluoro-phenyl)-9.10-dihydro-phenanthrenediol-(9.10t) (424-83-9)

Guidance literature:

With sodium amalgam; diethyl ether; at 20 ℃;

DOI:10.1021/ja01309a041

Reference yield:

9,10-phenanthrenequinone (84-11-7) + 4-flourophenylmagnesium bromide (352-13-6) → (+/-)-9r.10t-bis-(4-fluoro-phenyl)-9.10-dihydro-phenanthrenediol-(9.10c) (424-83-9)

Guidance literature:

With diethyl ether; benzene;

DOI:10.1021/ja01309a041

Reference yield:

9r.10c-bis-(4-fluoro-phenyl)-9.10-dihydro-phenanthrenediol-(9.10t) (424-83-9) → 10,10-bis-(4-fluoro-phenyl)-10H-phenanthren-9-one (426-71-1)

Guidance literature:

With acetic acid; acetyl chloride;

DOI:10.1021/ja01309a041

upstream raw materials:

2,2'-bis-(4-fluoro-benzoyl)-biphenyl

9,10-phenanthrenequinone

4-flourophenylmagnesium bromide

Downstream raw materials:

10,10-bis-(4-fluoro-phenyl)-10H-phenanthren-9-one