CID 16213827

Base Information

• Chemical Name: CID 16213827
• CAS No.: 12083-24-8
• Molecular Formula: C10H8 Cr O3
• Molecular Weight: 228.168
• Hs Code.: 29310099
• Mol file: 12083-24-8.mol

Synonyms:

Chemical Property of CID 16213827

Chemical Property:

• Melting Point: 78-82 °C(lit.)
• Flash Point: 170 °F
• PSA: 0.00000
• LogP: 1.37100
• Storage Temp.: Flammables area
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 227.987849
• Heavy Atom Count: 14
• Complexity: 95.2

Purity/Quality:

98%,99%, ^*data from raw suppliers

(TOLUENE)TRICARBONYLCHROMIUM 95.00% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: F,Xn
• Statements: 11-20/21/22
• Safety Statements: 16-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1=CC=CC=C1.[C-]#[O+].[C-]#[O+].[C-]#[O+].[Cr]

Technology Process of CID 16213827

There total 45 articles about CID 16213827 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

chromium(0) hexacarbonyl (199620-14-9,13007-92-6) + toluene (108-88-3,15644-74-3,16713-13-6) → tricarbonyl(η(6)-toluene)chromium (12083-24-8)

Guidance literature:

With catalyst: dimethyl succinate; In decalin; byproducts: CO; refluxing for 2.3 h (catalyst: dimethyl succinate); freezing out at -18°C or quick chromy. of the decaline soln. on a SiO2 column;

DOI:10.1016/0022-328X(91)80046-M

Reference yield: 83.0%

chromium(0) hexacarbonyl (199620-14-9,13007-92-6) + toluene (108-88-3,15644-74-3,16713-13-6) → tricarbonyl(η(6)-toluene)chromium (12083-24-8) + chromium(II) acetate (628-52-4,17593-70-3)

Guidance literature:

With acetic acid; In decalin; refluxing for 2.75 h;

DOI:10.1016/0022-328X(91)80047-N

Reference yield: 75.0%

tricarbonyl(η4:2-7,8-diphenyl-9-N-cyano-9-azabicyclo[4.2.1]-nona-2,4,7-triene)-chromium(0) (460719-09-9) → tricarbonyl(η(6)-toluene)chromium (12083-24-8) + 7,8-diphenyl-9-N-cyano-9-azabicyclo[4.2.1]-nona-2,4,7-triene

Guidance literature:

In toluene; (N2); refluxing a soln. of chromium complex in toluene for 10 min; evapn., thin layer chromy. (SiO2, hexane/CH2Cl2 1:1); elem. anal.;

DOI:10.1016/S0022-328X(02)01369-4

upstream raw materials:

chromium⁽⁰⁾ hexacarbonyl

toluene

4-methylphenylboronic acid

tri(4-tolyl)boroxine

Downstream raw materials:

(trans-stilbene)tricarbonylchromium

(C₆H₅CH₂C(O)C₆H₅)Cr(CO)3

C₆H₅CH₂CH(OH)C₆H₅Cr(CO)3

(η6-p-xylene)tricarbonylchromium(0)

Refernces

• 1、 Chaffee, Karen,Sheridan, John B.,Aistars, Arnis. "Photoinduced [6 + 2] cycloadditions of alkynes to tricarbonyl(cycloheptatriene)chromium(0)". . p. 18 - 19. Retrieved 1992.
• 2、 Patsalides, E.,Pratten, S. J.,Robards, K.. "Stability and the gas chromatography of alkyl-substituted η6-benzenetricarbonylchromium(0) complexes". . p. 169 - 180. Retrieved 1989.
• 3、 Fowles,Jenkins. "The reactions of group VI metal carbonyls with pyrrolidine, piperazine, and morpholine". . p. 257 - 259. Retrieved 1964.
• 4、 Goti, Andrea,Semmelhack, Martin F.. "Direct synthesis of (η6-arene)-tricarbonylchromium complexes by arene displacement from tricarbonyl(η5-1-methylpyrrole)chromium(0)". . p. C4 - C7. Retrieved 1994.
• 5、 Orlova,Nekrasov,Petrovskii,Ezernitskaya,Magdesieva,Milovanov,Butin. "Reactivity of some "ladder" type complexes under conditions of metallation". . p. 1785 - 1788. Retrieved 1998.
• 6、 Razuvaev, G. A.,Artemov, A. N.,Kasatkina, T. G.,Poselenova, E. N.. "". . . Retrieved 1982.
• 7、 Dery, Martin,Lefebvre, Louis-Philippe D.,Aissa, Kevin,Spino, Claude. "N -heteropolycyclic compounds from the formal intramolecular (4 + 1)-cycloaddition of chromium aminocarbenes". supporting information. p. 5456 - 5459. Retrieved 2013/11/19.
• 8、 -. "SYSTEM AND METHOD FOR SUPPRESSING SUBLIMATION OF MATERIALS DURING CHEMICAL TRANSFORMATION AT HIGH TEMPERATURES". Page/Page column 2. . Retrieved 2009/12/27.