Poly(oxy-1,2-ethanediyloxycarbonyl-2,6-naphthalenediylcarbonyl)

Base Information

• Chemical Name: Poly(oxy-1,2-ethanediyloxycarbonyl-2,6-naphthalenediylcarbonyl)
• CAS No.: 24968-11-4
• Molecular Formula: C₃₈H₅₂O₁₄
• Molecular Weight: 732.822
• Mol file: 24968-11-4.mol

Synonyms:Poly(oxyethyleneoxycarbonyl-2,6-naphthylenecarbonyl)(8CI); 70WXS; A 400; A 400 (polyester); Dimethyl 2,6-naphthalate-ethyleneglycol copolymer, SRU; Dimethyl 2,6-naphthalenedicarboxylate-ethylene glycolpolymer, SRU; Dimethyl naphthalene-2,6-dicarboxylae-ethylene glycol copolymersru; Eastman 14991; Ethylene glycol-2,6-naphthalenedicarboxylic acid chloridecopolymer, SRU; Ethylene glycol-2,6-naphthalenedicarboxylic acid copolymer,sru; Ethylene glycol-2,6-naphthalenedicarboxylic acid polymer, SRU; Ethyleneglycol-2,6-naphthalenedicarboxylic acid, SRU; Ethylene glycol-2,6-naphthalicacid copolymer, SRU; Ethylene glycol-2,6-naphthalic acid polymer, SRU; Ethyleneglycol-dimethyl 2,6-naphthalenedicarboxylate copolymer, sru; Ethyleneglycol-methyl 2,6-naphthalenedicarboxylate polymer, SRU; FQ-QBA; FS 405Z; G01S; HPEN; HiPertuf 35000; HiPertuf 40043; HiPertuf 92004; K 1030; KP 785;Kadalex; Kaladex; Kaladex 1000; Kaladex 1020; Kaladex 1030; Kaladex 2000;Kaladex 2030; Kaladex PEN; Kaladex S 1020/500; Kalidar 4353; Kalidar X 70;Melinex ST 506; NC 900Z; NS 653A; NXP 1500; Neotex Q 65EF; Novapex FS 405Z; P 100;PEN; PEN (polyester); PEN 14491; PN 510; PN 510 (polyester); PN 520; PN 640; PN650; Poly(ethylene 2,6-naphthalate); Poly(ethylene 2,6-naphthalate), SRU;Poly(ethylene 2,6-naphthalenedicarboxylate), SRU; Poly(ethylene naphthalate);Poly(oxycarbonyl-2,6-naphthalenediylcarbonyloxy-1,2-ethanediyl); Polyclear N100; Polyclear P 100; Q 34E5.0; Q 51; Q 51-38; Q 51C12; Q 65; Q 65A; Q 65FA;Q-Film; Q-Polymer; SPE 107; Skynex; TK 20; TK 20 (polyester); TN 8040; TN8050SC; TN 8055; TN 8060; TN 8065; TN 8065D2; TN 8065S; TN 8070; TN 8756; TR8060; TRB-PT; Teijin Q; Teonex; Teonex 8065; Teonex 8065S; Teonex Film Q 51;Teonex N 8056S; Teonex Q 01; Teonex Q 51; Teonex Q 51C; Teonex Q 51DW; Teonex Q51DW50; Teonex Q 56; Teonex Q 65; Teonex Q 65A; Teonex Q 65AF; Teonex Q 65F;Teonex Q 65FA; Teonex Q 81; Teonex Q 83; Teonex Q 83-50; Teonex TN 8050; TeonexTN 8050SC; Teonex TN 8065; Teonex TN 8065S; Teonex TN 8756;

Chemical Property of Poly(oxy-1,2-ethanediyloxycarbonyl-2,6-naphthalenediylcarbonyl)

Chemical Property:

• Melting Point: 280.5 °C
• Density: 1.349 g/cm3

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Poly(oxy-1,2-ethanediyloxycarbonyl-2,6-naphthalenediylcarbonyl)

There total 16 articles about Poly(oxy-1,2-ethanediyloxycarbonyl-2,6-naphthalenediylcarbonyl) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

2,6-Naphthalenedicarboxylic acid (1141-38-4) + O-propargyl triethylene glycol (208827-90-1) → bis(2-{2-[2-(prop-2-yn-1-yloxy)ethoxy]ethoxy}ethyl) naphthalene-2,6-dicarboxylate (24968-11-4)

Guidance literature:

With triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; at 20 ℃; for 16h; Inert atmosphere;

DOI:10.1002/ejoc.201700640

Reference yield: 64.0%

2,6-Naphthalenedicarboxylic acid (1141-38-4) + 3,6,9,12-tetraoxapentadec-14-yn-1-ol (87450-10-0) → di(3,6,9,12-tetraoxapentadec-14-yn-1-yl) naphthalene-2,6-dicarboxylate (24968-11-4)

Guidance literature:

With triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; at 20 ℃; for 16h; Inert atmosphere;

DOI:10.1002/ejoc.201700640

Reference yield: 59.0%

2,2′-[({[({[(5-azido-1,3-phenylene)bis(1H-1,2,3-triazole-4,1-diyl)]bis(ethane-2,1-diyl)}bis(oxy) )-bis(ethane-2,1-diyl)]bis(oxy)}bis(ethane-2,1-diyl))bis(oxy)]bis(ethan-1-ol) + di(3,6,9,12-tetraoxapentadec-14-yn-1-yl) naphthalene-2,6-dicarboxylate (24968-11-4) + 8',12',16',18',27',31',35',37'-octamethoxy-1,1,1'',1''-tetraethyldispiro(piperidinium-4,13'-[1,6,20,25]tetraoxa[6.1.6.1]paracyclophane-32',4''-piperidinium) dichloride → C86H122N18O28 (24968-11-4) + C86H122N18O28*C58H84N2O12(2+)*2Cl(1-)

Guidance literature:

With copper(II) sulfate; sodium L-ascorbate; 3-[4-[[bis[[1-(3-hydroxypropyl)triazol-4-yl]methyl]amino]methyl]triazol-1-yl]propan-1-ol; In water; at 20 ℃; for 5.33333h; Catalytic behavior; Inert atmosphere;

DOI:10.1002/ejoc.201700640

upstream raw materials:

2-(prop-2-ynyloxy)ethanol

dimethyl 2,6-naphthalenedicarboxylate

2-(2-(prop-2-ynyloxy)ethoxy)ethanol

2,6-Naphthalenedicarboxylic acid

Refernces

• 1、 Aeschi, Yves,Drayss-Orth, Sylvie,Valá?ek, Michal,Raps, Felix,H?ussinger, Daniel,Mayor, Marcel. "Assembly of [2]Rotaxanes in Water". . p. 4091 - 4103. Retrieved 2017/08/07.