Technology Process of 2-(4-chloro-2-phenylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
There total 5 articles about 2-(4-chloro-2-phenylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate;
In
dimethyl sulfoxide;
at 90 - 100 ℃;
for 16h;
Inert atmosphere;
- Guidance literature:
-
In
1,3,5-trimethyl-benzene;
at 155 ℃;
for 16h;
regioselective reaction;
Inert atmosphere;
DOI:10.1055/s-0031-1291142
- Guidance literature:
-
Multi-step reaction with 3 steps
1: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; caesium carbonate / water; 1,4-dioxane / 12 h / 90 - 100 °C / Inert atmosphere
2: pyridine / dichloromethane / 1 h / 0 - 15 °C
3: potassium acetate; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride / dimethyl sulfoxide / 16 h / 90 - 100 °C / Inert atmosphere
With
pyridine; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate; caesium carbonate;
In
1,4-dioxane; dichloromethane; water; dimethyl sulfoxide;